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Chemical Bonding and Molecular Structure

NEET 2016 (Phase 2)MCQMedium📈 Topic in 75% papers+4−1
Ques. 1NEET 2016 (Phase 2)

Among the following, which one is a wrong statement ?

  1. PH5 and BiCl5 do not exist.
  2. p -d bonds are present in SO2.
  3. SeF4 and CH4 have same shape.
  4. I3+ has bent geometry.

Answer

(3) SeF4 and CH4 have same shape.

Solution

(1) Correct: PH5 is not formed (H cannot make P use its d-orbitals) and BiCl5 is not formed (inert pair effect ⇒ +3 state of Bi is stable).

(2) Correct: SO2 has one p -p and one p -d bond.

(3) Wrong: SeF4 ⇒ 4 bp + 1 lp, sp3d ⇒ see-saw; CH4 ⇒ 4 bp, sp3 ⇒ tetrahedral.

(4) Correct: I3+ ⇒ central I has 2 bp + 2 lp, sp3 ⇒ bent.

Answer: (3)

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Ques. 2AIPMT 2015

In which of the following pairs, both the species are not isostructural ?

  1. Diamond, Silicon carbide
  2. NH3, PH3
  3. XeF4, XeO4
  4. SiCl4, PCl4+
Ques. 3AIPMT 2015

Decreasing order of stability of O2, O2-, O2+ and O22- is

  1. O22- > O2- > O2 > O2+
  2. O2 > O2+ > O22- > O2-
  3. O2- > O22- > O2+ > O2
  4. O2+ > O2 > O2- > O22-
Ques. 4AIPMT 2015 (Cancelled)

Which of the following pairs of ions are isoelectronic and isostructural ?

  1. SO32-, NO3-
  2. ClO3-, SO32-
  3. CO32-, SO32-
  4. ClO3-, CO32-
Ques. 5AIPMT 2015 (Cancelled)

The correct bond order in the following species is

  1. O2+ < O2- < O22+
  2. O2- < O2+ < O22+
  3. O22+ < O2+ < O2-
  4. O22+ < O2- < O2+
Ques. 6AIPMT 2015 (Cancelled)

Which of the following options represents the correct bond order ?

  1. O2- > O2 < O2+
  2. O2- < O2 > O2+
  3. O2- > O2 > O2+
  4. O2- < O2 < O2+
Ques. 7AIPMT 2015 (Cancelled)

Maximum bond angle at nitrogen is present in which of the following ?

  1. NO2+
  2. NO3-
  3. NO2
  4. NO2-
Ques. 8AIPMT 2015 (Cancelled)

Which of the following species contains equal number of σ- and π-bonds ?

  1. (CN)2
  2. CH2(CN)2
  3. HCO3-
  4. XeO4
Ques. 9AIPMT 2014

Which of the following molecules has the maximum dipole moment?

  1. CO2
  2. CH4
  3. NH3
  4. NF3
Ques. 10AIPMT 2014

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2
Ques. 11NEET 2013

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-

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