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Chemical Bonding and Molecular Structure

AIPMT 2014MCQEasy📈 Topic in 75% papers+4−1
Ques. 1AIPMT 2014

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2

Answer

(2) NO3-

Solution

N3- and CO2: 2 σ-bond pairs, no lone pair on central atom ⇒ sp, linear.

NO2-: 2 bond pairs + 1 lone pair on N ⇒ sp2, bent (V-shaped).

NO3-: 3 bond pairs, no lone pair on N ⇒ sp2, plane triangular (trigonal planar).

Answer: (2)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2NEET 2013

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-
Ques. 3NEET 2013

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4
Ques. 4NEET 2013

Which of the following is paramagnetic?

  1. CN-
  2. NO+
  3. CO
  4. O2-
Ques. 5NEET 2013

Which one of the following molecules contains no bond?

  1. SO2
  2. NO2
  3. CO2
  4. H2O
Ques. 6NEET 2013 (Karnataka)

The pair of species that has the same bond order in the following is

  1. CO, NO+
  2. NO-, CN-
  3. O2, N2
  4. O2, B2
Ques. 7NEET 2013 (Karnataka)

In which of the following pair both the species have sp3 hybridization ?

  1. SiF4, BeH2
  2. NF3, H2O
  3. NF3, BF3
  4. H2S, BF3
Ques. 8NEET 2013 (Karnataka)

In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.

  1. O2 O2+
  2. C2 C2+
  3. NO NO+
  4. N2 N2+
Ques. 9AIPMT 2012 (Mains)

During change of O2 to O2- ion, the electron adds on which one of the following orbitals ?

  1. * orbital
  2. orbital
  3. * orbital
  4. orbital
Ques. 10AIPMT 2012 (Mains)

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  1. NO < O2- < C22- < He2+
  2. O2- < NO < C22- < He2+
  3. C22- < He2+ < O2- < NO
  4. He2+ < O2- < NO < C22-
Ques. 11AIPMT 2012 (Prelims)

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?

  1. [BCl3 and BrCl3]
  2. [NH3 and NO3-]
  3. [NF3 and BF3]
  4. [BF4- and NH4+]

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