Amines

The major product Z formed in the following sequence of reactions is : [figure] (X = monochlorinated product)

1. C2H5-N=N-OH
2. C2H5OH
3. C2H5NO2
4. C2H5NH2

Select the reagents that reduce nitriles to primary amines. Choose the correct answer from the options given below.

1. A, B and C only
2. A, D and E only
3. A, C and D only
4. B, D and E only

Given below are two statements: In light of the above statements, choose the most appropriate answer from the options given below.

1. Statement I is incorrect but Statement II is correct
2. Both Statement I and Statement II are correct
3. Both Statement I and Statement II are incorrect
4. Statement I is correct but Statement II is incorrect

Identify the reactions which give aniline as the major product. Choose the correct answer from the options given below.

1. C and D only
2. A and B only
3. B and D only
4. A and C only

The correct order of decreasing basic strength of the given amines is:

1. N-ethylethanamine > ethanamine > N-methylaniline > benzenamine
2. benzenamine > ethanamine > N-methylaniline > N-ethylethanamine
3. N-methylaniline > benzenamine > ethanamine > N-ethylethanamine
4. N-ethylethanamine > ethanamine > benzenamine > N-methylaniline

Predict the major product 'P' in the following sequence of reactions- [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below:

1. Statement I is correct but Statement II is incorrect
2. Statement I is incorrect but Statement II is correct
3. Both Statement I and Statement II are correct
4. Both Statement I and Statement II are incorrect

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below:

1. Both statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is correct but Statement II is false
4. Statement I is incorrect but Statement II is true

Identify the major product C formed in the following reaction sequence : CH3-CH2-CH2-I NaCN A [Partial hydrolysis]OH- B [Br2]NaOH (major)C

1. propylamine
2. butylamine
3. butanamide
4. -bromobutanoic acid

The major product X formed in the following reaction sequence is : [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The major product D formed in the following reaction sequence is : [figure]

1. [figure]
2. [figure]
3. CH3CH2OH
4. CH3CH2Cl

The compound that does not undergo Friedel-Crafts alkylation reaction but gives a positive carbylamine test is :

1. Aniline
2. Pyridine
3. N-methylaniline
4. Triethylamine

Identify the product in the following reaction: [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Which of the following reactions will NOT give primary amine as the product?

1. CH3CN [ (ii) H3O ](i) LiAlH4 Product
2. CH3NC [ (ii) H3O ](i) LiAlH4 Product
3. CH3CONH2 [ (ii) H3O ](i) LiAlH4 Product
4. CH3CONH2 Br2/KOH Product

Given below are two statements In the light of the above statements, choose the most appropriate answer from the options given below.

1. Both Statement I and Statement II are correct.
2. Both Statement I and Statement II are incorrect.
3. Statement I is correct but Statement II is incorrect.
4. Statement I is incorrect but Statement II is correct.

The product formed from the following reaction sequence is [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The product formed from the following reaction sequence is : [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Match List-I with List-II : Choose the correct answer from the options given below :

1. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
2. (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
3. (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
4. (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)

Identify the compound that will react with Hinsberg's reagent to give a solid which dissolves in alkali.

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The reagent 'R' in the given sequence of chemical reaction is : [figure]

1. CuCN/KCN
2. H2O
3. CH3CH2OH
4. HI

Which of the following amine will give the carbylamine test?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The correct order of the basic strength of methyl substituted amines in aqueous solution is :

1. (CH3)3N > (CH3)2NH > CH3NH2
2. CH3NH2 > (CH3)2NH > (CH3)3N
3. (CH3)2NH > CH3NH2 > (CH3)3N
4. (CH3)3N > CH3NH2 > (CH3)2NH

Nitration of aniline in strong acidic medium also gives m-nitroaniline because

1. in spite of substituents nitro group always goes to only m-position
2. in electrophilic substitution reactions amino group is meta directive
3. in absence of substituents nitro group always goes to m-position
4. in acidic (strong) medium aniline is present as anilinium ion

The correct increasing order of basic strength for the following compounds is [figure]

1. III < I < II
2. III < II < I
3. II < I < III
4. II < III < I

Which of the following reactions is appropriate for converting acetamide to methanamine?

1. Hoffmann hypobromamide reaction
2. Stephen's reaction
3. Gabriel phthalimide synthesis
4. Carbylamine reaction

The correct statement regarding the basicity of arylamines is

1. arylamines are generally more basic than alkylamines because of aryl group
2. arylamines are generally more basic than alkylamines, because the nitrogen atom in arylamines is sp-hybridised
3. arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalised by interaction with the aromatic ring -electron system
4. arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalised by interaction with the aromatic ring -electron system.

Which one of the following nitro-compounds does not react with nitrous acid?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

A given nitrogen-containing aromatic compound 'A' reacts with Sn/HCl, followed by HNO2 to give an unstable compound 'B'. 'B', on treatment with phenol, forms a beautiful coloured compound 'C' with the molecular formula C12H10N2O. The structure of compound 'A' is

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The following reaction [figure] is known by the name

1. Perkin's reaction
2. Acetylation reaction
3. Schotten-Baumann reaction
4. Friedel-Craft's reaction

Method by which aniline cannot be prepared is

1. degradation of benzamide with bromine in alkaline solution
2. reduction of nitrobenzene with H2/Pd in ethanol
3. potassium salt of phthalimide treated with chlorobenzene followed by hydrolysis with aqueous NaOH solution
4. hydrolysis of phenylisocyanide with acidic solution.