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Amines

NEET (UG) 2022MCQEasy📈 Topic in 12% papers+4−1
Ques. 1NEET (UG) 2022

Given below are two statements In the light of the above statements, choose the most appropriate answer from the options given below.

  1. Both Statement I and Statement II are correct.
  2. Both Statement I and Statement II are incorrect.
  3. Statement I is correct but Statement II is incorrect.
  4. Statement I is incorrect but Statement II is correct.

Answer

(3) Statement I is correct but Statement II is incorrect.

Solution

Statement I: As per NCERT, primary aliphatic amines react with nitrous acid to form highly unstable aliphatic diazonium salts, which decompose at once to give alcohol and nitrogen gas:

RNH2 + HNO2 NaNO2 + HCl [R-N2+Cl-] H2O ROH + N2 + HCl. Correct.

Statement II: Primary aromatic amines give arenediazonium salts, which are stable only for a short time in solution at low temperature (273–278 K); they are not stable above 300 K. Incorrect.

Answer: (3)

Keep practising — Amines

Ques. 2NEET (UG) 2022

The product formed from the following reaction sequence is [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 3NEET (UG) 2022 (Phase 2)

The product formed from the following reaction sequence is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4NEET (UG) 2022 (Phase 2)

Match List-I with List-II : Choose the correct answer from the options given below :

  1. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
  2. (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
  3. (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
  4. (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
Ques. 5NEET (UG) 2021

Identify the compound that will react with Hinsberg's reagent to give a solid which dissolves in alkali.

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6NEET (UG) 2021

The reagent 'R' in the given sequence of chemical reaction is : [figure]

  1. CuCN/KCN
  2. H2O
  3. CH3CH2OH
  4. HI
Ques. 7NEET (UG) 2020

Which of the following amine will give the carbylamine test?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 8NEET (UG) 2019

The correct order of the basic strength of methyl substituted amines in aqueous solution is :

  1. (CH3)3N > (CH3)2NH > CH3NH2
  2. CH3NH2 > (CH3)2NH > (CH3)3N
  3. (CH3)2NH > CH3NH2 > (CH3)3N
  4. (CH3)3N > CH3NH2 > (CH3)2NH
Ques. 9NEET 2018

Nitration of aniline in strong acidic medium also gives m-nitroaniline because

  1. in spite of substituents nitro group always goes to only m-position
  2. in electrophilic substitution reactions amino group is meta directive
  3. in absence of substituents nitro group always goes to m-position
  4. in acidic (strong) medium aniline is present as anilinium ion
Ques. 10NEET 2017

The correct increasing order of basic strength for the following compounds is [figure]

  1. III < I < II
  2. III < II < I
  3. II < I < III
  4. II < III < I
Ques. 11NEET 2017

Which of the following reactions is appropriate for converting acetamide to methanamine?

  1. Hoffmann hypobromamide reaction
  2. Stephen's reaction
  3. Gabriel phthalimide synthesis
  4. Carbylamine reaction

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