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Chemical Bonding and Molecular Structure

AIPMT 2014MCQEasy📈 Topic in 12% papers+4−1
Ques. 1AIPMT 2014

Which of the following molecules has the maximum dipole moment?

  1. CO2
  2. CH4
  3. NH3
  4. NF3

Answer

(3) NH3

Solution

CO2 (linear) and CH4 (tetrahedral) are symmetrical ⇒ μ = 0.

In NH3 the lone-pair moment and the N–H bond moments point in the same direction ⇒ they add up ( = 4.90 10-30 C m).

In NF3 the N–F bond moments oppose the lone-pair moment ⇒ small resultant ( = 0.80 10-30 C m).

∴ NH3 has the maximum dipole moment.

Answer: (3)

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Ques. 2AIPMT 2014

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2
Ques. 3NEET 2013

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-
Ques. 4NEET 2013

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4
Ques. 5NEET 2013

Which of the following is paramagnetic?

  1. CN-
  2. NO+
  3. CO
  4. O2-
Ques. 6NEET 2013

Which one of the following molecules contains no bond?

  1. SO2
  2. NO2
  3. CO2
  4. H2O
Ques. 7NEET 2013 (Karnataka)

The pair of species that has the same bond order in the following is

  1. CO, NO+
  2. NO-, CN-
  3. O2, N2
  4. O2, B2
Ques. 8NEET 2013 (Karnataka)

In which of the following pair both the species have sp3 hybridization ?

  1. SiF4, BeH2
  2. NF3, H2O
  3. NF3, BF3
  4. H2S, BF3
Ques. 9NEET 2013 (Karnataka)

In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.

  1. O2 O2+
  2. C2 C2+
  3. NO NO+
  4. N2 N2+
Ques. 10AIPMT 2012 (Mains)

During change of O2 to O2- ion, the electron adds on which one of the following orbitals ?

  1. * orbital
  2. orbital
  3. * orbital
  4. orbital
Ques. 11AIPMT 2012 (Mains)

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  1. NO < O2- < C22- < He2+
  2. O2- < NO < C22- < He2+
  3. C22- < He2+ < O2- < NO
  4. He2+ < O2- < NO < C22-

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