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Chemical Bonding and Molecular Structure

AIPMT 2015MCQEasy📈 Topic in 75% papers+4−1
Ques. 1AIPMT 2015

In which of the following pairs, both the species are not isostructural ?

  1. Diamond, Silicon carbide
  2. NH3, PH3
  3. XeF4, XeO4
  4. SiCl4, PCl4+

Answer

(3) XeF4, XeO4

Solution

(1) Diamond and silicon carbide both have a three-dimensional network of tetrahedrally bonded (sp3) atoms ⇒ isostructural.

(2) NH3 and PH3: 3 bond pairs + 1 lone pair ⇒ both trigonal pyramidal.

(3) XeF4: 4 bond pairs + 2 lone pairs (sp3d2) ⇒ square planar

XeO4: 4 σ bonds, no lone pair (sp3) ⇒ tetrahedral

⇒ Not isostructural.

(4) SiCl4 and PCl4+: 4 bond pairs, no lone pair ⇒ both tetrahedral.

Answer: (3)

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Ques. 2AIPMT 2015

Decreasing order of stability of O2, O2-, O2+ and O22- is

  1. O22- > O2- > O2 > O2+
  2. O2 > O2+ > O22- > O2-
  3. O2- > O22- > O2+ > O2
  4. O2+ > O2 > O2- > O22-
Ques. 3AIPMT 2015 (Cancelled)

Which of the following pairs of ions are isoelectronic and isostructural ?

  1. SO32-, NO3-
  2. ClO3-, SO32-
  3. CO32-, SO32-
  4. ClO3-, CO32-
Ques. 4AIPMT 2015 (Cancelled)

The correct bond order in the following species is

  1. O2+ < O2- < O22+
  2. O2- < O2+ < O22+
  3. O22+ < O2+ < O2-
  4. O22+ < O2- < O2+
Ques. 5AIPMT 2015 (Cancelled)

Which of the following options represents the correct bond order ?

  1. O2- > O2 < O2+
  2. O2- < O2 > O2+
  3. O2- > O2 > O2+
  4. O2- < O2 < O2+
Ques. 6AIPMT 2015 (Cancelled)

Maximum bond angle at nitrogen is present in which of the following ?

  1. NO2+
  2. NO3-
  3. NO2
  4. NO2-
Ques. 7AIPMT 2015 (Cancelled)

Which of the following species contains equal number of σ- and π-bonds ?

  1. (CN)2
  2. CH2(CN)2
  3. HCO3-
  4. XeO4
Ques. 8AIPMT 2014

Which of the following molecules has the maximum dipole moment?

  1. CO2
  2. CH4
  3. NH3
  4. NF3
Ques. 9AIPMT 2014

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2
Ques. 10NEET 2013

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-
Ques. 11NEET 2013

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4

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