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Chemical Bonding and Molecular Structure

AIPMT 2015MCQEasy📈 Topic in 62% papers+4−1
Ques. 1AIPMT 2015

Decreasing order of stability of O2, O2-, O2+ and O22- is

  1. O22- > O2- > O2 > O2+
  2. O2 > O2+ > O22- > O2-
  3. O2- > O22- > O2+ > O2
  4. O2+ > O2 > O2- > O22-

Answer

(4) O2+ > O2 > O2- > O22-

Solution

Bond order = 12(Nb - Na); O2 has 16 electrons with Nb = 10.

O2+ (15 e⁻): Na = 5 ⇒ B.O. = 10 - 52 = 2.5

O2 (16 e⁻): Na = 6 ⇒ B.O. = 10 - 62 = 2

O2- (17 e⁻): Na = 7 ⇒ B.O. = 10 - 72 = 1.5

O22- (18 e⁻): Na = 8 ⇒ B.O. = 10 - 82 = 1

∵ Stability increases with bond order,

∴ O2+ > O2 > O2- > O22-

Answer: (4)

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Ques. 2AIPMT 2015 (Cancelled)

Which of the following pairs of ions are isoelectronic and isostructural ?

  1. SO32-, NO3-
  2. ClO3-, SO32-
  3. CO32-, SO32-
  4. ClO3-, CO32-
Ques. 3AIPMT 2015 (Cancelled)

The correct bond order in the following species is

  1. O2+ < O2- < O22+
  2. O2- < O2+ < O22+
  3. O22+ < O2+ < O2-
  4. O22+ < O2- < O2+
Ques. 4AIPMT 2015 (Cancelled)

Which of the following options represents the correct bond order ?

  1. O2- > O2 < O2+
  2. O2- < O2 > O2+
  3. O2- > O2 > O2+
  4. O2- < O2 < O2+
Ques. 5AIPMT 2015 (Cancelled)

Maximum bond angle at nitrogen is present in which of the following ?

  1. NO2+
  2. NO3-
  3. NO2
  4. NO2-
Ques. 6AIPMT 2015 (Cancelled)

Which of the following species contains equal number of σ- and π-bonds ?

  1. (CN)2
  2. CH2(CN)2
  3. HCO3-
  4. XeO4
Ques. 7AIPMT 2014

Which of the following molecules has the maximum dipole moment?

  1. CO2
  2. CH4
  3. NH3
  4. NF3
Ques. 8AIPMT 2014

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2
Ques. 9NEET 2013

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-
Ques. 10NEET 2013

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4
Ques. 11NEET 2013

Which of the following is paramagnetic?

  1. CN-
  2. NO+
  3. CO
  4. O2-

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