In a period, the first ionisation enthalpy of the element at extreme left and the negative electron gain enthalpy of the extreme right element, except noble gases, are respectively.
- lowest and lowest
- highest and lowest
- lowest and highest
- highest and highest
Answer
(3) lowest and highest
Solution
At the extreme left of a period is an alkali metal, with one electron outside a noble-gas core and the largest atom of the period, so it has the lowest first ionisation enthalpy in the period.
At the extreme right (except the noble gas) is a halogen, which needs only one electron to complete its octet and has small size and high Zeff, so it has the most negative, i.e. the highest negative, electron gain enthalpy.
∴ The values are lowest and highest respectively.
Answer: (3)