Haloalkanes and Haloarenes

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Both Statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is true but Statement II is false
4. Statement I is false but Statement II is true

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Both Statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is true but Statement II is false
4. Statement I is false but Statement II is true

RMgI when treated with ice cold water liberated a gas which occupied 1.4 dm3/g at STP. The gas produced is further reacted with iodine in presence of HIO3 to give compound (X). Compound (X) in presence of Na and dry ether produced compound (Y). Molar mass of compound (Y) is g mol-1. (Nearest integer)

Match the LIST-I with LIST-II Choose the correct answer from the options given below :

1. A-I, B-IV, C-III, D-II
2. A-III, B-I, C-IV, D-II
3. A-IV, B-II, C-I, D-III
4. A-I, B-III, C-II, D-IV

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Both Statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is true but Statement II is false
4. Statement I is false but Statement II is true

Correct statements regarding alkyl halides (R–X) among the following are : Choose the correct answer from the options given below :

1. A, B and C Only
2. B and D Only
3. A and E Only
4. D and E Only

Which of the following reactions is NOT correctly represented?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Identify the correct statements : The presence of -NO2 group in benzene ring Choose the correct answer from the options given below :

1. A and D Only
2. B and D Only
3. C and A Only
4. B and C Only

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below

1. Statement I is false but Statement II is true
2. Statement I is true but Statement II is false
3. Both Statement I and Statement II are true
4. Both Statement I and Statement II are false

Match the List-I with List-II Choose the correct answer from the options given below :

1. A-III, B-IV, C-I, D-II
2. A-IV, B-I, C-III, D-II
3. A-III, B-IV, C-II, D-I
4. A-I, B-II, C-IV, D-III

As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene? Choose the correct answer from the options given below :

1. B, C and E Only
2. A, C and E Only
3. B, C and D Only
4. A, D and E Only

The correct order of the rate of reaction of the following reactants with nucleophile by SN1 mechanism is : (Given : Structures I and II are rigid) [figure]

1. I < II < III < IV
2. II < I < III < IV
3. III < I < II < IV
4. IV < III < II < I

The correct order of reactivity of CH3Br in methanol with the following nucleophiles is F-, I-, C2H5O- and C6H5O-

1. I- > C2H5O- > C6H5O- > F-
2. I- > F- > C6H5O- > C2H5O-
3. I- > C6H5O- > F- > C2H5O-
4. I- > C2H5O- > F- > C6H5O-

The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is : CH3Br + Nu- CH3Nu + Br-

1. ClO4- > CH3COO- > OH- > PhO-
2. OH- > PhO- > CH3COO- > ClO4-
3. CH3COO- > PhO- > OH- > ClO4-
4. PhO- > OH- > CH3COO- > ClO4-

The correct order of reactivity of the following benzyl halides towards reaction with KCN is : [figure]

1. a > b > c > d
2. b > a > d > c
3. b > a > c > d
4. a > b > d > c

The reactions which cannot be applied to prepare an alkene by elimination, are Choose the correct answer from the options given below:

1. B & E Only
2. B, C & D Only
3. A, C & D Only
4. B & D Only

Match List - I with List - II. Choose the correct answer from the options given below :

1. A-II, B-III, C-I, D-IV
2. A-III, B-IV, C-II, D-I
3. A-IV, B-III, C-I, D-II
4. A-IV, B-III, C-II, D-I

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

1. Both Statement I and Statement II are incorrect
2. Both Statement I and Statement II are correct
3. Statement I is incorrect but Statement II is correct
4. Statement I is correct but Statement II is incorrect

In the following series of reactions identify the major products A & B respectively : [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Match List-I with List-II. Choose the correct answer from the options given below:

1. (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
2. (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
3. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
4. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

[figure] Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major product P is 80\% whereas Q is 100\%. Mass of product Q obtained is g. (Given molar mass in g mol-1 H : 1, C : 12, O : 16, Br : 80)

In the following substitution reaction : [figure] Product 'P' formed is :

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Which among the following halides will generate the most stable carbocation in the nucleophilic substitution reaction?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The products A and B in the following reactions, respectively are A AgNO2 CH3-CH2-CH2-Br AgCN B

1. CH3-CH2-CH2-ONO, CH3-CH2-CH2-CN
2. CH3-CH2-CH2-NO2, CH3-CH2-CH2-CN
3. CH3-CH2-CH2-ONO, CH3-CH2-CH2-NC
4. CH3-CH2-CH2-NO2, CH3-CH2-CH2-NC

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below

1. Both Statement I and Statement II are correct
2. Statement I is incorrect but Statement II is correct
3. Both Statement I and Statement II are incorrect
4. Statement I is correct but Statement II is incorrect

The product B formed in the following reaction sequence is: [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The major product of the following reaction is: [figure]

1. 6-Phenylhepta-3,5-diene
2. 6-Phenylhepta-2,4-diene
3. 2-Phenylhepta-2,4-diene
4. 2-Phenylhepta-2,5-diene

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

1. Statement I is false but Statement II is true
2. Statement I is true but Statement II is false
3. Both Statement I and Statement II are false
4. Both Statement I and Statement II are true

The structure of the major product formed in the following reaction is : [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Match the List - I with List - II Choose the correct answer from the options given below:

1. A-II, B-III, C-I, D-IV
2. A-II, B-I, C-III, D-IV
3. A-IV, B-I, C-III, D-II
4. A-IV, B-III, C-I, D-II