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Haloalkanes and Haloarenes

JEE Main 2026 (Online) 21st January Evening ShiftMCQMedium📈 Topic in 31% papers+4−1
Ques. 1JEE Main 2026, 21 January (Evening Shift)

The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is : CH3Br + Nu- CH3Nu + Br-

  1. ClO4- > CH3COO- > OH- > PhO-
  2. OH- > PhO- > CH3COO- > ClO4-
  3. CH3COO- > PhO- > OH- > ClO4-
  4. PhO- > OH- > CH3COO- > ClO4-

Answer

(2) OH- > PhO- > CH3COO- > ClO4-

Solution

CH3Br (a methyl halide) reacts by SN2; the rate depends on the strength of the nucleophile.

All four nucleophiles attack through oxygen, so nucleophilicity runs parallel to basicity.

Acid strength of conjugate acids: HClO4 > CH3COOH > C6H5OH > H2O

Basicity: OH- > PhO- > CH3COO- > ClO4-

The negative charge is localised on O in OH-, delocalised into the ring in PhO-, over two O atoms in CH3COO- and over four O atoms in ClO4-.

Rate: OH- > PhO- > CH3COO- > ClO4-

Answer: (2)

Keep practising — Haloalkanes and Haloarenes

Ques. 2JEE Main 2026, 21 January (Evening Shift)

The correct order of reactivity of the following benzyl halides towards reaction with KCN is : [figure]

  1. a > b > c > d
  2. b > a > d > c
  3. b > a > c > d
  4. a > b > d > c
Ques. 3JEE Main 2025, 7 April (Morning Shift)

The reactions which cannot be applied to prepare an alkene by elimination, are Choose the correct answer from the options given below:

  1. B & E Only
  2. B, C & D Only
  3. A, C & D Only
  4. B & D Only
Ques. 4JEE Main 2025, 7 April (Evening Shift)

Match List - I with List - II. Choose the correct answer from the options given below :

  1. A-II, B-III, C-I, D-IV
  2. A-III, B-IV, C-II, D-I
  3. A-IV, B-III, C-I, D-II
  4. A-IV, B-III, C-II, D-I
Ques. 5JEE Main 2025, 4 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are incorrect
  2. Both Statement I and Statement II are correct
  3. Statement I is incorrect but Statement II is correct
  4. Statement I is correct but Statement II is incorrect
Ques. 6JEE Main 2025, 3 April (Evening Shift)

In the following series of reactions identify the major products A & B respectively : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 7JEE Main 2025, 2 April (Evening Shift)

Match List-I with List-II. Choose the correct answer from the options given below:

  1. (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
  2. (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
  3. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
  4. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
Ques. 8JEE Main 2025, 2 April (Evening Shift)

[figure] Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major product P is 80\% whereas Q is 100\%. Mass of product Q obtained is g. (Given molar mass in g mol-1 H : 1, C : 12, O : 16, Br : 80)

Ques. 9JEE Main 2025, 29 January (Morning Shift)

In the following substitution reaction : [figure] Product 'P' formed is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10JEE Main 2025, 29 January (Evening Shift)

Which among the following halides will generate the most stable carbocation in the nucleophilic substitution reaction?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 11JEE Main 2025, 28 January (Morning Shift)

The products A and B in the following reactions, respectively are A AgNO2 CH3-CH2-CH2-Br AgCN B

  1. CH3-CH2-CH2-ONO, CH3-CH2-CH2-CN
  2. CH3-CH2-CH2-NO2, CH3-CH2-CH2-CN
  3. CH3-CH2-CH2-ONO, CH3-CH2-CH2-NC
  4. CH3-CH2-CH2-NO2, CH3-CH2-CH2-NC

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