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Haloalkanes and Haloarenes

JEE Main 2025 (Online) 23rd January Morning ShiftMatchingEasy📈 Topic in 16% papers+4−1
Ques. 1JEE Main 2025, 23 January (Morning Shift)

Match the List - I with List - II Choose the correct answer from the options given below:

  1. A-II, B-III, C-I, D-IV
  2. A-II, B-I, C-III, D-IV
  3. A-IV, B-I, C-III, D-II
  4. A-IV, B-III, C-I, D-II

Answer

(4) A-IV, B-III, C-I, D-II

Solution

Concept: match each name reaction with its product.

A. Swarts: metallic fluoride ⇒ ethyl fluoride ⇒ IV

[figure]

B. Sandmeyer: CuCN replaces N2 ⇒ cyanobenzene ⇒ III

[figure]

C. Wurtz–Fittig: Na, dry ether joins aryl and alkyl ⇒ ethylbenzene ⇒ I

[figure]

D. Finkelstein: NaI, dry acetone ⇒ ethyl iodide ⇒ II

[figure]

∴ A-IV, B-III, C-I, D-II

Answer: (4)

Keep practising — Haloalkanes and Haloarenes

Ques. 2JEE Main 2025, 23 January (Evening Shift)

The ascending order of relative rate of solvolysis of following compounds is : [figure]

  1. (C) < (D) < (B) < (A)
  2. (D) < (A) < (B) < (C)
  3. (D) < (B) < (A) < (C)
  4. (C) < (B) < (A) < (D)
Ques. 3JEE Main 2025, 22 January (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are incorrect
  2. Both Statement I and Statement II are correct
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
Ques. 4JEE Main 2025, 22 January (Evening Shift)

[figure] The maximum number of RBr producing 2-methylbutane by above sequence of reactions is . (Consider the structural isomers only)

  1. 5
  2. 3
  3. 4
  4. 1

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