Atomos Test Generator Free PYQs ExamsMy practice Log in / Sign up free

Haloalkanes and Haloarenes

Previous year questions with solutions · 2025 – 2026

33Questions
25Papers covered
3.16%Weightage 2026▼ 16.7% vs last year
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202615190.793.16% ▼ 16.7% vs last year
202518190.953.79%

26 questions · newest paper first

Ques. 1JEE Main 2026, 8 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
Ques. 2JEE Main 2026, 6 April (Morning Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
Ques. 3JEE Main 2026, 2 April (Morning Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
Ques. 4JEE Main 2026, 2 April (Evening Shift)

Correct statements regarding alkyl halides (R–X) among the following are : Choose the correct answer from the options given below :

  1. A, B and C Only
  2. B and D Only
  3. A and E Only
  4. D and E Only
Ques. 5JEE Main 2026, 28 January (Evening Shift)

Which of the following reactions is NOT correctly represented?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6JEE Main 2026, 28 January (Evening Shift)

Identify the correct statements : The presence of -NO2 group in benzene ring Choose the correct answer from the options given below :

  1. A and D Only
  2. B and D Only
  3. C and A Only
  4. B and C Only
Ques. 7JEE Main 2026, 24 January (Morning Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
Ques. 8JEE Main 2026, 22 January (Morning Shift)

As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene? Choose the correct answer from the options given below :

  1. B, C and E Only
  2. A, C and E Only
  3. B, C and D Only
  4. A, D and E Only
Ques. 9JEE Main 2026, 22 January (Morning Shift)

The correct order of the rate of reaction of the following reactants with nucleophile by SN1 mechanism is : (Given : Structures I and II are rigid) [figure]

  1. I < II < III < IV
  2. II < I < III < IV
  3. III < I < II < IV
  4. IV < III < II < I
Ques. 10JEE Main 2026, 22 January (Morning Shift)

The correct order of reactivity of CH3Br in methanol with the following nucleophiles is F-, I-, C2H5O- and C6H5O-

  1. I- > C2H5O- > C6H5O- > F-
  2. I- > F- > C6H5O- > C2H5O-
  3. I- > C6H5O- > F- > C2H5O-
  4. I- > C2H5O- > F- > C6H5O-
Ques. 11JEE Main 2026, 21 January (Evening Shift)

The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is : CH3Br + Nu- CH3Nu + Br-

  1. ClO4- > CH3COO- > OH- > PhO-
  2. OH- > PhO- > CH3COO- > ClO4-
  3. CH3COO- > PhO- > OH- > ClO4-
  4. PhO- > OH- > CH3COO- > ClO4-
Ques. 12JEE Main 2026, 21 January (Evening Shift)

The correct order of reactivity of the following benzyl halides towards reaction with KCN is : [figure]

  1. a > b > c > d
  2. b > a > d > c
  3. b > a > c > d
  4. a > b > d > c
Ques. 13JEE Main 2025, 7 April (Morning Shift)

The reactions which cannot be applied to prepare an alkene by elimination, are Choose the correct answer from the options given below:

  1. B & E Only
  2. B, C & D Only
  3. A, C & D Only
  4. B & D Only
Ques. 14JEE Main 2025, 4 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are incorrect
  2. Both Statement I and Statement II are correct
  3. Statement I is incorrect but Statement II is correct
  4. Statement I is correct but Statement II is incorrect
Ques. 15JEE Main 2025, 3 April (Evening Shift)

In the following series of reactions identify the major products A & B respectively : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 16JEE Main 2025, 29 January (Morning Shift)

In the following substitution reaction : [figure] Product 'P' formed is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 17JEE Main 2025, 29 January (Evening Shift)

Which among the following halides will generate the most stable carbocation in the nucleophilic substitution reaction?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 18JEE Main 2025, 28 January (Morning Shift)

The products A and B in the following reactions, respectively are A AgNO2 CH3-CH2-CH2-Br AgCN B

  1. CH3-CH2-CH2-ONO, CH3-CH2-CH2-CN
  2. CH3-CH2-CH2-NO2, CH3-CH2-CH2-CN
  3. CH3-CH2-CH2-ONO, CH3-CH2-CH2-NC
  4. CH3-CH2-CH2-NO2, CH3-CH2-CH2-NC
Ques. 19JEE Main 2025, 28 January (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below

  1. Both Statement I and Statement II are correct
  2. Statement I is incorrect but Statement II is correct
  3. Both Statement I and Statement II are incorrect
  4. Statement I is correct but Statement II is incorrect
Ques. 20JEE Main 2025, 28 January (Evening Shift)

The product B formed in the following reaction sequence is: [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 21JEE Main 2025, 28 January (Evening Shift)

The major product of the following reaction is: [figure]

  1. 6-Phenylhepta-3,5-diene
  2. 6-Phenylhepta-2,4-diene
  3. 2-Phenylhepta-2,4-diene
  4. 2-Phenylhepta-2,5-diene
Ques. 22JEE Main 2025, 24 January (Morning Shift)

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are false
  4. Both Statement I and Statement II are true
Ques. 23JEE Main 2025, 24 January (Evening Shift)

The structure of the major product formed in the following reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 24JEE Main 2025, 23 January (Evening Shift)

The ascending order of relative rate of solvolysis of following compounds is : [figure]

  1. (C) < (D) < (B) < (A)
  2. (D) < (A) < (B) < (C)
  3. (D) < (B) < (A) < (C)
  4. (C) < (B) < (A) < (D)
Ques. 25JEE Main 2025, 22 January (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are incorrect
  2. Both Statement I and Statement II are correct
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
Ques. 26JEE Main 2025, 22 January (Evening Shift)

[figure] The maximum number of RBr producing 2-methylbutane by above sequence of reactions is . (Consider the structural isomers only)

  1. 5
  2. 3
  3. 4
  4. 1