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Equilibrium

JEE Main 2025 (Online) 23rd January Morning ShiftNumericalEasy📈 Topic in 9% papers+4
Ques. 1JEE Main 2025, 23 January (Morning Shift)

If 1 mM solution of ethylamine produces pH=9, then the ionization constant (Kb) of ethylamine is 10-x. The value of x is (nearest integer). [The degree of ionization of ethylamine can be neglected with respect to unity.]

Answer

7

Solution

Concept: Kb C 2 and [OH-]=C ⇒ Kb= [OH-]2C

pH=9 pOH=5 [OH-]=10-5 M, C=10-3 M

Kb= 10-1010-3=10-7 ⇒ x=7

Answer: 7

Keep practising — Equilibrium

Ques. 2JEE Main 2025, 23 January (Evening Shift)

pH of water is 7 at 25 C. If water is heated to 80 C, it's pH will :

  1. Decrease
  2. Remains the same
  3. Increase
  4. H+ concentration increases, OH- concentration decreases
Ques. 3JEE Main 2025, 23 January (Evening Shift)

Consider the reaction X2Y(g) X2(g) + 12Y2(g) The equation representing correct relationship between the degree of dissociation (x) of X2Y(g) with its equilibrium constant Kp is . Assume x to be very very small.

  1. x = [3] KpP
  2. x = [3] Kp2P
  3. x = [3] 2 Kp2P
  4. x = [3] 2KpP
Ques. 4JEE Main 2025, 22 January (Morning Shift)

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of CO2 is converted into CO on addition of graphite. If total pressure at equilibrium is 0.8 atm, then Kp is :

  1. 0.18 atm
  2. 0.3 atm
  3. 3 atm
  4. 1.8 atm
Ques. 5JEE Main 2025, 22 January (Evening Shift)

The molar solubility(s) of zirconium phosphate with molecular formula ( Zr4+ )3 ( PO43- )4 is given by relation :

  1. ( Ksp5348 )1/6
  2. ( Ksp8435 )1/7
  3. ( Ksp6912 )1/7
  4. ( Ksp9612 )1/3
Ques. 6JEE Main 2024, 9 April (Evening Shift)

For a sparingly soluble salt AB2, the equilibrium concentrations of A2+ ions and B- ions are 1.2 10-4 M and 0.24 10-3 M, respectively. The solubility product of AB2 is :

  1. 0.069 10-12
  2. 0.276 10-12
  3. 6.91 10-12
  4. 27.65 10-12
Ques. 7JEE Main 2024, 8 April (Morning Shift)

For the given hypothetical reactions, the equilibrium constants are as follows : X Y; K1 = 1.0 Y Z; K2 = 2.0 Z W; K3 = 4.0 The equilibrium constant for the reaction X W is

  1. 12.0
  2. 8.0
  3. 6.0
  4. 7.0
Ques. 8JEE Main 2024, 8 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are false
  2. Both Statement I and Statement II are true
  3. Statement I is false but Statement II is true
  4. Statement I is true but Statement II is false
Ques. 9JEE Main 2024, 6 April (Morning Shift)

At -20 and 1 atm pressure, a cylinder is filled with equal number of H2, I2 and HI molecules for the reaction H2(g) + I2(g) 2HI(g), the Kp for the process is x 10-1. x = . [Given : R = 0.082 L atm K-1 mol-1]

  1. 2
  2. 1
  3. 10
  4. 0.01
Ques. 10JEE Main 2024, 6 April (Evening Shift)

The ratio KpKC for the reaction : CO(g) + 12O2(g) CO2(g) is :

  1. 1
  2. (RT)1/2
  3. RT
  4. 1 RT
Ques. 11JEE Main 2024, 5 April (Morning Shift)

The following reaction occurs in the Blast furnace where iron ore is reduced to iron metal Fe2O3(s) + 3CO(g) Fe(l) + 3CO2(g) Using the Le Chatelier's principle, predict which one of the following will not disturb the equilibrium.

  1. Addition of CO2
  2. Removal of CO
  3. Addition of Fe2O3
  4. Removal of CO2

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