Atomos Test Generator Free PYQs ExamsMy practice Log in / Sign up free

Solutions

JEE Main 2025 (Online) 28th January Evening ShiftMCQMedium📈 Topic in 19% papers+4−1
Ques. 1JEE Main 2025, 28 January (Evening Shift)

Assume a living cell with 0.9% (w/w) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data upto first decimal place only) The cell will :

  1. shrink since solution is 0.45% (w/w) as a result of association of glucose molecules (due to hydrogen bonding)
  2. shrink since solution is 0.5% (w/w)
  3. show no change in volume since solution is 0.9% (w/w)
  4. swell up since solution is 1% (w/w)

Answer

Solution

Outside solution: equal mole fractions nglucose = nwater.

Take 1 mol of each: mass of glucose = 180 g, mass of water = 18 g.

% (w/w) of glucose = 180180 + 18 100 = 90.9\%

Cell sap: 0.9% (w/w) glucose, i.e. xglucose = 0.9/1800.9/180 + 99.1/18 9 10-4.

The outside solution is far more concentrated (hypertonic); water moves out of the cell by osmosis and the cell shrinks.

None of the options gives the correct concentration of the outside solution (90.9% w/w), so no option is fully correct; the question was awarded as bonus.

Answer: No option is correct (the cell shrinks).

Keep practising — Solutions

Ques. 2JEE Main 2025, 24 January (Morning Shift)

Consider the given plots of vapour pressure (VP) vs temperature (T/K). Which amongst the following options is correct graphical representation showing Tf, depression in the freezing point of a solvent in a solution?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 3JEE Main 2025, 24 January (Evening Shift)

The observed and normal molar masses of compound MX2 are 65.6 and 164 respectively. The percent degree of ionisation of MX2 is %. (Nearest integer)

Ques. 4JEE Main 2025, 23 January (Morning Shift)

CrCl3 xNH3 can exist as a complex. 0.1 molal aqueous solution of this complex shows a depression in freezing point of 0.558 C. Assuming 100% ionisation of this complex and coordination number of Cr is 6, the complex will be (Given Kf = 1.86 K kg mol-1)

  1. [Cr(NH3)5Cl]Cl2
  2. [Cr(NH3)4Cl2]Cl
  3. [Cr(NH3)6]Cl3
  4. [Cr(NH3)3Cl3]
Ques. 5JEE Main 2025, 23 January (Evening Shift)

When a non-volatile solute is added to the solvent, the vapour pressure of the solvent decreases by 10 mm of Hg. The mole fraction of the solute in the solution is 0.2. What would be the mole fraction of the solvent if decrease in vapour pressure is 20 mm of Hg ?

  1. 0.2
  2. 0.4
  3. 0.8
  4. 0.6
Ques. 6JEE Main 2025, 23 January (Evening Shift)

Consider a binary solution of two volatile liquid components 1 and 2. x1 and y1 are the mole fractions of component 1 in liquid and vapour phase, respectively. The slope and intercept of the linear plot of 1x1 vs 1y1 are given respectively as :

  1. P10P20, P10-P20P20
  2. P20P10, P20-P10P10
  3. P20P10, P10-P20P20
  4. P10P20, P20-P10P20
Ques. 7JEE Main 2025, 22 January (Morning Shift)

Arrange the following solutions in order of their increasing boiling points. (i) 10-4 M NaCl (ii) 10-4 M Urea (iii) 10-3 M NaCl (iv) 10-2 M NaCl

  1. (i) < (ii) < (iii) < (iv)
  2. (ii) < (i) < (iii) < (iv)
  3. (iv) < (iii) < (i) < (ii)
  4. (ii) < (i) (iii) < (iv)
Ques. 8JEE Main 2025, 22 January (Evening Shift)

Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is :

  1. 2.79 m
  2. 2 m
  3. 1.79 m
  4. 3 m
Ques. 9JEE Main 2024, 9 April (Morning Shift)

0.05 M CuSO4 when treated with 0.01 M K2Cr2O7 gives green colour solution of Cu2Cr2O7. The two solutions are separated as shown below : [SPM : Semi Permeable Membrane] [figure] Due to osmosis :

  1. Molarity of K2Cr2O7 solution is lowered.
  2. Green colour formation observed on side Y.
  3. Molarity of CuSO4 solution is lowered.
  4. Green colour formation observed on side X.
Ques. 10JEE Main 2024, 9 April (Morning Shift)

Molarity (M) of an aqueous solution containing x g of anhyd. CuSO4 in 500 mL solution at 32 is 2 10-1 M. Its molality will be 10-3 m. (nearest integer). [Given density of the solution = 1.25 g/mL]

Ques. 11JEE Main 2024, 9 April (Evening Shift)

The vapor pressure of pure benzene and methyl benzene at 27 C is given as 80 Torr and 24 Torr, respectively. The mole fraction of methyl benzene in vapor phase, in equilibrium with an equimolar mixture of those two liquids (ideal solution) at the same temperature is 10-2 (nearest integer)

All Solutions PYQs →

PDFDownload Solutions PYQs as PDF Free, with answer key and a QR code to every solution — print it or study offline⬇
All JEE Main Chemistry chapters