Principles Related to Practical Chemistry

During estimation of nitrogen by Dumas' method of compound X (0.42 g) [figure] mL of N2 gas will be liberated at STP. (nearest integer) (Given molar mass in g mol-1 : C : 12, H : 1, N : 14)

0.5 g of an organic compound on combustion gave 1.46 g of CO2 and 0.9 g of H2O. The percentage of carbon in the compound is . (Nearest integer) [Given : Molar mass (in g mol-1) C : 12, H : 1, O : 16]

Compounds that should not be used as primary standards in titrimetric analysis are : Choose the most appropriate answer from the options given below:

1. C, D and E Only
2. B and D Only
3. D and E Only
4. A, C and D Only

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at 300 K = 15 mm Hg)

1. 15.71\%
2. 17.46\%
3. 7.85\%
4. 20.95\%

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

1. A, D and E only
2. A, B and C only
3. B, D and E only
4. C, D and E only

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

1. 20.87
2. 12.57
3. 1.257
4. 18.67

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

1. Sulphide ion
2. Sulphite ion
3. Sulphate ion
4. Sodium ion

Match List-I with List-II. Choose the correct answer from the options given below:

1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

1. (B) and (D) Only
2. (A), (B) and (C) Only
3. (A) and (B) Only
4. (A) and (C) Only

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is true but Statement II is false
2. Statement I is false but Statement II is true
3. Both Statement I and Statement II are false
4. Both Statement I and Statement II are true