Principles Related to Practical Chemistry

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

1. 20.87
2. 12.57
3. 1.257
4. 18.67

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

1. Sulphide ion
2. Sulphite ion
3. Sulphate ion
4. Sodium ion

Match List-I with List-II. Choose the correct answer from the options given below:

1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

1. (B) and (D) Only
2. (A), (B) and (C) Only
3. (A) and (B) Only
4. (A) and (C) Only

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is true but Statement II is false
2. Statement I is false but Statement II is true
3. Both Statement I and Statement II are false
4. Both Statement I and Statement II are true

In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is 10-1\%. (Molar mass : O = 16, S = 32, Ba = 137 in g mol-1)

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

1. Statement I is false but Statement II is true
2. Statement I is true but Statement II is false
3. Both Statement I and Statement II are true
4. Both Statement I and Statement II are false

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

1. Cr3+
2. Ti3+
3. Ni2+
4. Mn2+

The purification method based on the following physical transformation is : (X)Solid Heat (X)Vapour Cool (X)Solid

1. Extraction
2. Crystallization
3. Distillation
4. Sublimation

Identify the inorganic sulphides that are yellow in colour : Choose the correct answer from the options given below :

1. (D) and (E) only
2. (A) and (B) only
3. (A), (D) and (E) only
4. (A) and (C) only