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Principles Related to Practical Chemistry

JEE Main 2025 (Online) 29th January Morning ShiftMCQEasy📈 Topic in 42% papers+4−1
Ques. 1JEE Main 2025, 29 January (Morning Shift)

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

  1. (B) and (D) Only
  2. (A), (B) and (C) Only
  3. (A) and (B) Only
  4. (A) and (C) Only

Answer

(3) (A) and (B) Only

Solution

As per NCERT, o-nitrophenol is steam volatile due to intramolecular hydrogen bonding, while p-nitrophenol is less volatile due to intermolecular hydrogen bonding (association).

(A) o-Nitrophenol: –OH and -NO2 are ortho intramolecular H-bond steam volatile

(B) o-Nitroaniline: –NH2 and -NO2 are ortho intramolecular H-bond steam volatile

(C) and (D) are both 3-aminophenol: –OH and –NH2 are meta, so no intramolecular H-bond; strong intermolecular H-bonding not steam volatile

(A) and (B) only

Answer: (3)

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Ques. 2JEE Main 2025, 29 January (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is true but Statement II is false
  2. Statement I is false but Statement II is true
  3. Both Statement I and Statement II are false
  4. Both Statement I and Statement II are true
Ques. 3JEE Main 2025, 29 January (Evening Shift)

In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is 10-1\%. (Molar mass : O = 16, S = 32, Ba = 137 in g mol-1)

Ques. 4JEE Main 2025, 28 January (Morning Shift)

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
Ques. 5JEE Main 2025, 28 January (Morning Shift)

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

  1. Cr3+
  2. Ti3+
  3. Ni2+
  4. Mn2+
Ques. 6JEE Main 2025, 28 January (Evening Shift)

The purification method based on the following physical transformation is : (X)Solid Heat (X)Vapour Cool (X)Solid

  1. Extraction
  2. Crystallization
  3. Distillation
  4. Sublimation
Ques. 7JEE Main 2025, 28 January (Evening Shift)

Identify the inorganic sulphides that are yellow in colour : Choose the correct answer from the options given below :

  1. (D) and (E) only
  2. (A) and (B) only
  3. (A), (D) and (E) only
  4. (A) and (C) only
Ques. 8JEE Main 2025, 24 January (Morning Shift)

Given below are two statements I and II. In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is true but Statement II is false
  2. Statement I is false but Statement II is true
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
Ques. 9JEE Main 2025, 24 January (Morning Shift)

Among the following cations, the number of cations which will give characteristic precipitate in their identification tests with K4[Fe(CN)6] is . Cu2+, Fe3+, Ba2+, Ca2+, NH4+, Mg2+, Zn2+

Ques. 10JEE Main 2025, 24 January (Evening Shift)

Find the compound 'A' from the following reaction sequences. A aqua-regiaB [(2) AcOH](1) KNO2, NH4OH yellow ppt

  1. NiS
  2. MnS
  3. ZnS
  4. CoS
Ques. 11JEE Main 2025, 24 January (Evening Shift)

In Carius method of estimation of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide (AgBr). The percentage of Bromine in the organic compound is 10-1\% (Nearest integer). (Given : Molar mass of Ag is 108 and Br is 80 g mol-1)

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