p-Block Elements (Group 15–18)

Which is the correct statement for the given acids?

1. Phosphinic acid is a monoprotic acid while phosphonic acid is a diprotic acid.
2. Phosphinic acid is a diprotic acid while phosphonic acid is a monoprotic acid.
3. Both are diprotic acids.
4. Both are triprotic acids.

Which one of the following orders is correct for the bond dissociation enthalpy of halogen molecules?

1. Br2 > I2 > F2 > Cl2
2. F2 > Cl2 > Br2 > I2
3. I2 > Br2 > Cl2 > F2
4. Cl2 > Br2 > F2 > I2

When copper is heated with conc. HNO3 it produces

1. Cu(NO3)2, NO and NO2
2. Cu(NO3)2 and N2O
3. Cu(NO3)2 and NO2
4. Cu(NO3)2 and NO

Among the following the correct order of acidity is

1. HClO2 < HClO < HClO3 < HClO4
2. HClO4 < HClO2 < HClO < HClO3
3. HClO3 < HClO4 < HClO2 < HClO
4. HClO < HClO2 < HClO3 < HClO4

Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following reactions does not show oxidizing behaviour?

1. Cu + 2H2SO4 CuSO4 + SO2 + 2H2O
2. 3S + 2H2SO4 3SO2 + 2H2O
3. C + 2H2SO4 CO2 + 2SO2 + 2H2O
4. CaF2 + H2SO4 CaSO4 + 2HF

Strong reducing behavior of H3PO2 is due to

1. high electron gain enthalpy of phosphorus
2. high oxidation state of phosphorus
3. presence of two -OH groups and one P-H bond
4. presence of one -OH group and two P-H bonds.

The variation of the boiling points of the hydrogen halides is in the order HF > HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?

1. There is strong hydrogen bonding between HF molecules.
2. The bond energy of HF molecules is greater than in other hydrogen halides.
3. The effect of nuclear shielding is much reduced in fluorine which polarises the HF molecule.
4. The electronegativity of fluorine is much higher than for other elements in the group.

Which of the statements given below is incorrect?

1. O3 molecule is bent.
2. ONF is isoelectronic with O2N-
3. OF2 is an oxide of fluorine.
4. Cl2O7 is an anhydride of perchloric acid.

Nitrogen dioxide and sulphur dioxide have some properties in common. Which property is shown by one of these compounds, but not by the other?

1. Is soluble in water.
2. Is used as a food preservative.
3. Forms 'acid-rain'.
4. Is a reducing agent.

Acidity of diprotic acids in aqueous solutions increases in the order

1. H2S < H2Se < H2Te
2. H2Se < H2S < H2Te
3. H2Te < H2S < H2Se
4. H2Se < H2Te < H2S

Which is the strongest acid in the following?

1. HClO4
2. H2SO3
3. H2SO4
4. HClO3

Roasting of sulphides gives the gas X as a byproduct. This is a colourless gas with choking smell of burnt sulphur and causes great damage to respiratory organs as a result of acid rain. Its aqueous solution is acidic, acts as a reducing agent and its acid has never been isolated. The gas X is

1. CO2
2. SO3
3. H2S
4. SO2

Identify the incorrect statement, regarding the molecule XeO4:

1. XeO4 molecule is square planar.
2. There are four p -d bonds.
3. There are four sp3-p, bonds.
4. XeO4 molecule is tetrahedral.

In which of the following arrangements the given sequence is not strictly according to the property indicated against it?

1. HF < HCl < HBr < HI : increasing acidic strength
2. H2O < H2S < H2Se < H2Te : increasing pKa values
3. NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
4. CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power

Which of the following statements is not valid for oxoacids of phosphorus?

1. Orthophosphoric acid is used in the manufacture of triple superphosphate.
2. Hypophosphorous acid is a diprotic acid.
3. All oxoacids contain tetrahedral four coordinated phosphorus.
4. All oxoacids contain at least one P=O unit and one P-OH group.

Sulphur trioxide can be obtained by which of the following reactions?

1. CaSO4 + C
2. Fe2(SO4)3
3. S + H2SO4
4. H2SO4 + PCl5

How many bridging oxygen atoms are present in P4O10?

1. 6
2. 4
3. 2
4. 5

Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.

1. (A) (i); (B) (iv); (C) (ii); (D) (iii)
2. (A) (i); (B) (ii); (C) (iii); (D) (iv)
3. (A) (iv); (B) (iii); (C) (ii); (D) (i)
4. (A) (iv); (B) (ii); (C) (iii); (D) (i)

Oxidation states of P in H4P2O5, H4P2O6, H4P2O7 are respectively

1. +3, +5, +4
2. +5, +3, +4
3. +5, +4, +3
4. +3, +4, +5

Among the following which is the strongest oxidising agent?

1. Br2
2. I2
3. Cl2
4. F2

Which of the following arrangements do not give the correct picture of the trends indicated against them?

1. F2 > Cl2 > Br2 > I2 : Bond dissociation energy
2. F2 > Cl2 > Br2 > I2 : Electronegativity
3. F2 > Cl2 > Br2 > I2 : Oxidizing power
4. F2 > Cl2 > Br2 > I2 : Electron gain enthalpy

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

1. HOClO < HOCl < HOClO3 < HOClO2
2. HOClO2 < HOClO3 < HOClO < HOCl
3. HOClO3 < HOClO2 < HOClO < HOCl
4. HOCl < HOClO < HOClO2 < HOClO3

Which one of the following orders is not in accordance with the property stated against it ?

1. F2 > Cl2 > Br2 > I2 : Bond dissociation energy
2. F2 > Cl2 > Br2 > I2 : Oxidising power
3. HI > HBr > HCl > HF : Acidic property in water
4. F2 > Cl2 > Br2 > I2 : Electronegativity

Which one of the following orders is not in accordance with the property stated against it?

1. F2 > Cl2 > Br2 > I2 : Bond dissociation energy
2. F2 > Cl2 > Br2 > I2 : Oxidising power
3. HI > HBr > HCl > HF : Acidic property in water
4. F2 > Cl2 > Br2 > I2 : Electronegativity.

Which one of the following oxides is expected to exhibit paramagnetic behaviour?

1. CO2
2. SiO2
3. SO2
4. ClO2

What is the correct relationship between the pH of isomolar solutions of sodium oxide, Na2O (pH1), sodium sulphide, Na2S (pH2), sodium selenide, Na2Se (pH3) and sodium telluride Na2Te (pH4)?

1. pH1 > pH2 > pH3 > pH4
2. pH1 > pH2 pH3 > pH4
3. pH1 < pH2 < pH3 < pH4
4. pH1 < pH2 < pH3 pH4

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

1. HOClO < HOCl < HOClO3 < HOClO2
2. HOClO3 < HOClO2 < HOClO < HOCl
3. HOClO2 < HOClO3 < HOClO < HOCl
4. HOCl < HOClO < HOClO2 < HOClO3

Which one of the following statements is not true?

1. Among halide ions, iodide is the most powerful reducing agent.
2. Fluorine is the only halogen that does not show a variable oxidation state.
3. HOCl is a stronger acid than HOBr.
4. HF is a stronger acid than HCl.

Which of the following statement is true?

1. Silicon exhibits 4 coordination number in its compounds
2. Bond energy of F2 is less than Cl2
3. Mn(III) oxidation state is more stable than Mn(II) in aqueous state
4. Elements of 15th group show only +3 and +5 oxidation states

Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because

1. Zn acts as oxidising agent when it reacts with HNO3
2. HNO3 is weaker acid than H2SO4 and HCl
3. In electrochemical series Zn is above hydrogen
4. NO3- is reduced in preference to hydronium ion.