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p-Block Elements (Group 15–18)

AIPMT 2015 (Cancelled)MCQMedium📈 Topic in 38% papers+4−1
Ques. 1AIPMT 2015 (Cancelled)

Nitrogen dioxide and sulphur dioxide have some properties in common. Which property is shown by one of these compounds, but not by the other?

  1. Is soluble in water.
  2. Is used as a food preservative.
  3. Forms 'acid-rain'.
  4. Is a reducing agent.

Answer

(2) Is used as a food preservative.

Solution

Both NO2 and SO2 are acidic oxides, soluble in water:

2NO2 + H2O HNO3 + HNO2; SO2 + H2O H2SO3

⇒ both form acid rain.

Both can act as reducing agents (N in NO2 is +4 and can go to +5; S in SO2 is +4 and can go to +6).

As per NCERT, SO2 is used as an anti-chlor, disinfectant and preservative; NO2 is not used as a food preservative.

Answer: (2)

Keep practising — p-Block Elements (Group 15–18)

Ques. 2AIPMT 2014

Acidity of diprotic acids in aqueous solutions increases in the order

  1. H2S < H2Se < H2Te
  2. H2Se < H2S < H2Te
  3. H2Te < H2S < H2Se
  4. H2Se < H2Te < H2S
Ques. 3NEET 2013

Which is the strongest acid in the following?

  1. HClO4
  2. H2SO3
  3. H2SO4
  4. HClO3
Ques. 4NEET 2013

Roasting of sulphides gives the gas X as a byproduct. This is a colourless gas with choking smell of burnt sulphur and causes great damage to respiratory organs as a result of acid rain. Its aqueous solution is acidic, acts as a reducing agent and its acid has never been isolated. The gas X is

  1. CO2
  2. SO3
  3. H2S
  4. SO2
Out of syllabus
Ques. 5NEET 2013 (Karnataka)

Identify the incorrect statement, regarding the molecule XeO4:

  1. XeO4 molecule is square planar.
  2. There are four p -d bonds.
  3. There are four sp3-p, bonds.
  4. XeO4 molecule is tetrahedral.
Ques. 6AIPMT 2012 (Mains)

In which of the following arrangements the given sequence is not strictly according to the property indicated against it?

  1. HF < HCl < HBr < HI : increasing acidic strength
  2. H2O < H2S < H2Se < H2Te : increasing pKa values
  3. NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
  4. CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power
Ques. 7AIPMT 2012 (Prelims)

Which of the following statements is not valid for oxoacids of phosphorus?

  1. Orthophosphoric acid is used in the manufacture of triple superphosphate.
  2. Hypophosphorous acid is a diprotic acid.
  3. All oxoacids contain tetrahedral four coordinated phosphorus.
  4. All oxoacids contain at least one P=O unit and one P-OH group.
Ques. 8AIPMT 2012 (Prelims)

Sulphur trioxide can be obtained by which of the following reactions?

  1. CaSO4 + C
  2. Fe2(SO4)3
  3. S + H2SO4
  4. H2SO4 + PCl5
Ques. 9AIPMT 2010 (Mains)

How many bridging oxygen atoms are present in P4O10?

  1. 6
  2. 4
  3. 2
  4. 5
Ques. 10AIPMT 2010 (Mains)

Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.

  1. (A) (i); (B) (iv); (C) (ii); (D) (iii)
  2. (A) (i); (B) (ii); (C) (iii); (D) (iv)
  3. (A) (iv); (B) (iii); (C) (ii); (D) (i)
  4. (A) (iv); (B) (ii); (C) (iii); (D) (i)
Ques. 11AIPMT 2010 (Prelims)

Oxidation states of P in H4P2O5, H4P2O6, H4P2O7 are respectively

  1. +3, +5, +4
  2. +5, +3, +4
  3. +5, +4, +3
  4. +3, +4, +5

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