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d- and f-Block Elements

Previous year questions with solutions · 2024 – 2026

93Questions
52Papers covered
5.05%Weightage 2026▼ 4% vs last year
’24
’25
’26
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202624191.35.05% ▼ 4% vs last year
202525191.35.26% ▼ 28.2% vs last year
202444202.27.33%

20 questions · newest paper first

Ques. 1JEE Main 2026, 2 April (Evening Shift)

Number of paramagnetic ions among the following d- and f-block metal ions is . Mn2+, Cu2+, Zn2+, Yb2+, Sc3+, La3+, Gd3+, Lu3+, Ti4+, Ce4+ (Atomic number of Mn = 25, Cu = 29, Zn = 30, Yb = 70, Sc = 21, La = 57, Gd = 64, Lu = 71, Ti = 22, Ce = 58)

Ques. 2JEE Main 2026, 22 January (Evening Shift)

Among the following oxides of 3d elements, the number of mixed oxides are . Ti2O3, V2O4, Cr2O3, Mn3O4, Fe3O4, Fe2O3, Co3O4

Ques. 3JEE Main 2026, 21 January (Morning Shift)

Consider the following reactions : NaCl + K2Cr2O7 + H2SO4 A + KHSO4 + NaHSO4 + H2O A + NaOH B + NaCl + H2O B + H2SO4 + H2O2 C + Na2SO4 + H2O In the product 'C', 'X' is the number of O22- units, 'Y' is the total number of oxygen atoms present and 'Z' is the oxidation state of Cr. The value of X + Y + Z is .

Ques. 4JEE Main 2025, 4 April (Morning Shift)

KMnO4 acts as an oxidising agent in acidic medium. 'X' is the difference between the oxidation states of Mn in reactant and product. 'Y' is the number of 'd' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of X + Y is .

Ques. 5JEE Main 2025, 3 April (Morning Shift)

Consider the following reactions A + Little amountNaCl + H2SO4 CrO2Cl2 + Side Products CrO2Cl2(Vapour) + NaOH B + NaCl + H2O B + H+ C + H2O The number of terminal 'O' present in the compound 'C' is

Ques. 6JEE Main 2025, 3 April (Evening Shift)

Among Sc, Mn, Co and Cu, identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is BM (in nearest integer).

Ques. 7JEE Main 2025, 2 April (Evening Shift)

The spin-only magnetic moment value of Mn+ ion formed among Ni, Zn, Mn and Cu that has the least enthalpy of atomisation is . (in nearest integer) Here n is equal to the number of diamagnetic complexes among K2[NiCl4], [Zn(H2O)6]Cl2, K3[Mn(CN)6] and [Cu(PPh3)3I]

Ques. 8JEE Main 2025, 29 January (Morning Shift)

The molar mass of the water insoluble product formed from the fusion of chromite ore (FeCr2O4) with Na2CO3 in presence of O2 is g mol-1.

Ques. 9JEE Main 2025, 28 January (Evening Shift)

The spin only magnetic moment ( ) value (B.M.) of the compound with the strongest oxidising power among Mn2O3, TiO and VO is B.M. (Nearest integer).

Ques. 10JEE Main 2024, 9 April (Morning Shift)

Number of colourless lanthanoid ions among the following is . Eu3+, Lu3+, Nd3+, La3+, Sm3+

Ques. 11JEE Main 2024, 9 April (Evening Shift)

A transition metal 'M' among Sc, Ti, V, Cr, Mn and Fe has the highest second ionisation enthalpy. The spin-only magnetic moment value of M+ ion is BM (Nearest integer) (Given atomic number Sc : 21, Ti : 22, V : 23, Cr : 24, Mn : 25, Fe : 26)

Ques. 12JEE Main 2024, 8 April (Morning Shift)

The 'spin only' magnetic moment value of MO42- is BM. (Where M is a metal having least metallic radii. among Sc, Ti, V, Cr, Mn and Zn). (Given atomic number: Sc = 21, Ti = 22, V = 23, Cr = 24, Mn = 25 and Zn = 30)

Ques. 13JEE Main 2024, 6 April (Morning Shift)

The difference in the 'spin-only' magnetic moment values of KMnO4 and the manganese product formed during titration of KMnO4 against oxalic acid in acidic medium is BM. (nearest integer)

Ques. 14JEE Main 2024, 6 April (Morning Shift)

Among CrO, Cr2O3 and CrO3, the sum of spin-only magnetic moment values of basic and amphoteric oxides is 10-2 BM (nearest integer). (Given atomic number of Cr is 24 )

Ques. 15JEE Main 2024, 6 April (Evening Shift)

Among VO2+, MnO4- and Cr2O72-, the spin-only magnetic moment value of the species with least oxidising ability is BM (Nearest integer). (Given atomic number V = 23, Mn = 25, Cr = 24)

Ques. 16JEE Main 2024, 5 April (Morning Shift)

The spin-only magnetic moment value of the ion among Ti2+, V2+, Co3+ and Cr2+, that acts as strong oxidising agent in aqueous solution is BM (Near integer). (Given atomic numbers : Ti : 22, V : 23, Cr : 24, Co : 27)

Ques. 17JEE Main 2024, 5 April (Evening Shift)

The fusion of chromite ore with sodium carbonate in the presence of air leads to the formation of products A and B along with the evolution of CO2. The sum of spin-only magnetic moment values of A and B is B.M. (Nearest integer) [Given atomic number : C : 6, Na : 11, O : 8, Fe : 26, Cr : 24]

Ques. 18JEE Main 2024, 4 April (Morning Shift)

Consider the following reaction MnO2 + KOH + O2 A + H2O. Product 'A' in neutral or acidic medium disproportionate to give products 'B' and 'C' along with water. The sum of spin-only magnetic moment values of B and C is BM. (nearest integer) (Given atomic number of Mn is 25)

Ques. 19JEE Main 2024, 4 April (Evening Shift)

A first row transition metal with highest enthalpy of atomisation, upon reaction with oxygen at high temperature forms oxides of formula M2On (where n = 3, 4, 5). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is BM (near integer) (Given atomic number: Sc : 21, Ti : 22, V : 23, Cr : 24, Mn : 25, Fe : 26, Co : 27, Ni : 28, Cu : 29, Zn : 30)

Ques. 20JEE Main 2024, 31 January (Evening Shift)

In the reaction of potassium dichromate, potassium chloride and sulfuric acid (conc.), the oxidation state of the chromium in the product is (+) .