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d- and f-Block Elements

JEE Main 2024 (Online) 8th April Morning ShiftNumericalEasy📈 Topic in 34% papers+4
Ques. 1JEE Main 2024, 8 April (Morning Shift)

The 'spin only' magnetic moment value of MO42- is BM. (Where M is a metal having least metallic radii. among Sc, Ti, V, Cr, Mn and Zn). (Given atomic number: Sc = 21, Ti = 22, V = 23, Cr = 24, Mn = 25 and Zn = 30)

Answer

0

Solution

Metallic radii (pm): Sc 164, Ti 147, V 135, Cr 129, Mn 137, Zn 137; the least is Cr, so M = Cr.

In CrO42-: x + 4(−2) = −2, so x = +6

Cr6+ = [Ar] 3d0: no unpaired electron (n = 0)

∴ μ = n(n + 2) = 0 BM

Answer: 0

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Ques. 2JEE Main 2024, 8 April (Evening Shift)

The equilibrium Cr2O72- 2CrO42- is shifted to the right in :

  1. a weakly acidic medium
  2. a basic medium
  3. a neutral medium
  4. an acidic medium
Ques. 3JEE Main 2024, 8 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are false
  4. Both Statement I and Statement II are true
Ques. 4JEE Main 2024, 6 April (Morning Shift)

The number of elements from the following that do not belong to lanthanoids is Eu, Cm, Er, Tb, Yb and Lu

  1. 3
  2. 1
  3. 4
  4. 5
Ques. 5JEE Main 2024, 6 April (Morning Shift)

The difference in the 'spin-only' magnetic moment values of KMnO4 and the manganese product formed during titration of KMnO4 against oxalic acid in acidic medium is BM. (nearest integer)

Ques. 6JEE Main 2024, 6 April (Morning Shift)

Among CrO, Cr2O3 and CrO3, the sum of spin-only magnetic moment values of basic and amphoteric oxides is 10-2 BM (nearest integer). (Given atomic number of Cr is 24 )

Ques. 7JEE Main 2024, 6 April (Evening Shift)

Arrange the following elements in the increasing order of number of unpaired electrons in it. Choose the correct answer from the options given below :

  1. (A) < (D) < (C) < (B) < (E)
  2. (A) < (D) < (C) < (E) < (B)
  3. (B) < (C) < (D) < (E) < (A)
  4. (C) < (E) < (B) < (A) < (D)
Ques. 8JEE Main 2024, 6 April (Evening Shift)

Among VO2+, MnO4- and Cr2O72-, the spin-only magnetic moment value of the species with least oxidising ability is BM (Nearest integer). (Given atomic number V = 23, Mn = 25, Cr = 24)

Ques. 9JEE Main 2024, 5 April (Morning Shift)

The metal that shows highest and maximum number of oxidation state is :

  1. Co
  2. Mn
  3. Fe
  4. Ti
Ques. 10JEE Main 2024, 5 April (Morning Shift)

The spin-only magnetic moment value of the ion among Ti2+, V2+, Co3+ and Cr2+, that acts as strong oxidising agent in aqueous solution is BM (Near integer). (Given atomic numbers : Ti : 22, V : 23, Cr : 24, Co : 27)

Ques. 11JEE Main 2024, 5 April (Evening Shift)

The number of ions from the following that have the ability to liberate hydrogen from a dilute acid is . Ti2+, Cr2+ and V2+

  1. 1
  2. 2
  3. 3
  4. 0

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