Some Basic Concepts of Chemistry

For the given reaction; CaCO3 + 2HCl CaCl2 + H2O + CO2 If 90 g CaCO3 is added to 300 mL of HCl which contains 38.55% HCl by mass and has density 1.13 g mL-1, then which of the following option is correct? Given molar mass of H, Cl, Ca and O are 1, 35.5, 40 and 16 g mol-1 respectively.

1. 64.97 g of HCl remains unreacted
2. 60.32 g of HCl remains unreacted
3. 32.85 g of CaCO3 remains unreacted
4. 97.30 g of HCl reacted

A student has planned to prepare acetanilide from aniline using acetic anhydride. The student has started from 9.3 g of aniline. However, the student has managed to obtain 11 g of dry acetanilide. The % yield of this reaction is :-

1. 59.5\%
2. 72.5\%
3. 97.5\%
4. 81.5\%

x mg of pure HCl was used to make an aqueous solution. 25.0 mL of 0.1 M Ba(OH)2 solution is used when the HCl solution was titrated against it. The numerical value of x is 10-1. (Nearest integer) Given : Molar mass of HCl and Ba(OH)2 are 36.5 and 171.0 g mol-1 respectively.

In the reaction, 2Al(s) + 6HCl(aq) 2Al3+(aq) + 6Cl-(aq) + 3H2(g)

1. 12 L HCl(aq) is consumed for every 6 L H2(g) produced.
2. 11.2 L H2(g) at STP is produced for every mole of HCl consumed.
3. 33.6 L H2(g) is produced regardless of temperature and pressure for every mole of Al that reacts.
4. 67.2 L H2(g) at STP is produced for every mole of Al that reacts.

At T(K), 100 g of 98\% H2SO4 (w/w) aqueous solution is mixed with 100 g of 49\% H2SO4 (w/w) aqueous solution. What is the mole fraction of H2SO4 in the resultant solution? (Given : Atomic mass H = 1 u; S = 32 u; O = 16 u). (Assume that temperature after mixing remains constant)

1. 0.9
2. 0.663
3. 0.1
4. 0.337

A + 2B AB2 36.0 g of 'A' (Molar mass : 60 g mol-1) and 56.0 g of 'B' (Molar mass : 80 g mol-1) are allowed to react. Which of the following statements are correct ? Choose the correct answer from the options given below :

1. A and C Only
2. A and B Only
3. C and D Only
4. B and D Only

14.0 g of calcium metal is allowed to react with excess HCl at 1.0 atm pressure and 273 K. Which of the following statements is incorrect? [Given : Molar mass in g mol-1 of Ca – 40, Cl – 35.5, H – 1]

1. The limiting reagent is calcium metal.
2. 33.3 g of CaCl2 is produced.
3. 7.84 L of H2 gas is evolved.
4. 0.35 mol of H2 gas is evolved.

80 mL of a hydrocarbon on mixing with 264 mL of oxygen in a closed U-tube undergoes complete combustion. The residual gases after cooling to 273 K occupy 224 mL. When the system is treated with KOH solution, the volume decreases to 64 mL. The formula of the hydrocarbon is :

1. C2H2
2. C2H4
3. C4H10
4. C2H6

Aqueous HCl reacts with MnO2(s) to form MnCl2(aq), Cl2(g), and H2O(l). What is the weight (in g) of Cl2 liberated when 8.7 g of MnO2(s) is reacted with excess aqueous HCl solution? (Given Molar mass in g mol-1 Mn = 55, Cl = 35.5, O = 16, H = 1)

1. 14.2
2. 21.3
3. 7.1
4. 71

20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver nitrate solution. The molarity of the sodium iodide solution is M. (Nearest Integer value) (Given : Na = 23, I = 127, Ag = 108, N = 14, O = 16 g mol-1)