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Chemical Bonding and Molecular Structure

AIPMT 2009MCQEasy📈 Topic in 25% papers+4−1
Ques. 1AIPMT 2009

The energy absorbed by each molecule (A2) of a substance is 4.4 10-19 J and bond energy per molecule is 4.0 10-19 J. The kinetic energy of the molecule per atom will be

  1. 2.2 10-19 J
  2. 2.0 10-19 J
  3. 4.0 10-20 J
  4. 2.0 10-20 J

Answer

(4) 2.0 10-20 J

Solution

Part of the absorbed energy breaks the bond, and the rest appears as kinetic energy of the two atoms.

⇒ Kinetic energy per molecule = 4.4 10-19 - 4.0 10-19

= 0.4 10-19 J

∵ A2 2A, the energy is shared by two atoms,

∴ kinetic energy per atom = 0.4 10-192

= 2.0 10-20 J

Answer: (4)

Out of syllabus

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Ques. 2AIPMT 2009

In the case of alkali metals, the covalent character decreases in the order

  1. MF > MCl > MBr > MI
  2. MF > MCl > MI > MBr
  3. MI > MBr > MCl > MF
  4. MCl > MI > MBr > MF
Out of syllabus
Ques. 3AIPMT 2008

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  1. NO < O2- < C22- < He2+
  2. O2- < NO < C22- < He2+
  3. C22- < He2+ < O2- < NO
  4. He2+ < O2- < NO < C22-
Ques. 4AIPMT 2008

The correct order of increasing bond angles in the following triatomic species is

  1. NO2+ < NO2 < NO2-
  2. NO2+ < NO2- < NO2
  3. NO2- < NO2+ < NO2
  4. NO2- < NO2 < NO2+
Ques. 5AIPMT 2008

The angular shape of ozone molecule (O3) consists of

  1. 1σ and 1π bond
  2. 2σ and 1π bond
  3. 1σ and 2π bonds
  4. 2σ and 2π bonds
Ques. 6AIPMT 2007

In which of the following pairs, the two species are isostructural?

  1. SO32- and NO3-
  2. BF3 and NF3
  3. BrO3- and XeO3
  4. SF4 and XeF4
Ques. 7AIPMT 2007

The correct order of C-O bond length among CO, CO32-, CO2 is

  1. CO < CO32- < CO2
  2. CO32- < CO2 < CO
  3. CO < CO2 < CO32-
  4. CO2 < CO32- < CO
Ques. 8AIPMT 2006

Which of the following is not a correct statement?

  1. Multiple bonds are always shorter than corresponding single bonds.
  2. The electron-deficient molecules can act as Lewis acids.
  3. The canonical structures have no real existence.
  4. Every AB5 molecule does in fact have square pyramid structure.
Ques. 9AIPMT 2006

Which of the following is not isostructural with SiCl4 ?

  1. NH4+
  2. SCl4
  3. SO42-
  4. PO43-
Ques. 10AIPMT 2006

Which of the following species has a linear shape?

  1. O3
  2. NO2-
  3. SO2
  4. NO2+
Ques. 11AIPMT 2006

The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because

  1. in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these are in the same direction
  2. in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
  3. in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions
  4. in NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions.

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