Organic Chemistry – Some Basic Principles and Techniques

Match List - I with List - II. Choose the correct answer from the options given below :

1. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
2. (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
3. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
4. (A)-(III), (B)-(II), (C)-(I), (D)-(IV)

Total number of nucleophiles from the following is : NH3, PhSH, (H3C)2S, H2C=CH2, OH, H3O , (CH3)2 CO, [figure]

1. 4
2. 6
3. 5
4. 7

Total number of sigma ( ) and pi( ) bonds respectively present in hex-1-en-4-yne are:

1. 14 and 3
2. 11 and 3
3. 13 and 3
4. 3 and 13

The correct order of stability of following carbocations is : [figure]

1. A > B > C > D
2. C > B > A > D
3. B > C > A > D
4. C > A > B > D

Which one of the carbocations from the following is most stable?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

In the given structure, number of sp and sp2 hybridized carbon atoms present respectively are : [figure]

1. 3 and 5
2. 3 and 6
3. 4 and 5
4. 4 and 6

The hydrocarbon (X) with molar mass 80 g mol-1 and 90\% carbon has degree of unsaturation.

The correct stability order of the following species/molecules is : [figure]

1. q > r > p
2. q > p > r
3. p > q > r
4. r > q > p

The IUPAC name of the following compound is : [figure]

1. 5-Methoxycarbonyl-2-methylhexanoic acid
2. Methyl-5-carboxy-2-methylhexanoate.
3. 2-Carboxy-5-methoxycarbonylhexane.
4. Methyl-6-carboxy-2,5-dimethylhexanoate.

The most stable carbocation from the following is :

1. [figure]
2. [figure]
3. [figure]
4. [figure]