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Organic Chemistry – Some Basic Principles and Techniques

JEE Main 2025 (Online) 24th January Morning ShiftMCQMedium📈 Topic in 14% papers+4−1
Ques. 1JEE Main 2025, 24 January (Morning Shift)

Which one of the carbocations from the following is most stable?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(3) [figure]

Solution

+M of the O lone pair stabilises a cation; -I of F or C=O destabilises it.

(C): O is on the allyl system extra resonance form, all atoms with octet:

[figure] [figure]

(A) O not conjugated; (B) lone pair shared with C=O; (D) strong -I of F.

Answer: (3)

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Ques. 2JEE Main 2025, 24 January (Evening Shift)

In the given structure, number of sp and sp2 hybridized carbon atoms present respectively are : [figure]

  1. 3 and 5
  2. 3 and 6
  3. 4 and 5
  4. 4 and 6
Ques. 3JEE Main 2025, 24 January (Evening Shift)

The hydrocarbon (X) with molar mass 80 g mol-1 and 90\% carbon has degree of unsaturation.

Ques. 4JEE Main 2025, 23 January (Morning Shift)

The correct stability order of the following species/molecules is : [figure]

  1. q > r > p
  2. q > p > r
  3. p > q > r
  4. r > q > p
Ques. 5JEE Main 2025, 22 January (Morning Shift)

The IUPAC name of the following compound is : [figure]

  1. 5-Methoxycarbonyl-2-methylhexanoic acid
  2. Methyl-5-carboxy-2-methylhexanoate.
  3. 2-Carboxy-5-methoxycarbonylhexane.
  4. Methyl-6-carboxy-2,5-dimethylhexanoate.
Ques. 6JEE Main 2025, 22 January (Evening Shift)

The most stable carbocation from the following is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 7JEE Main 2025, 22 January (Evening Shift)

The alkane from below having two secondary hydrogens is :

  1. 2,2,4,5-Tetramethylheptane
  2. 2,2,4,4-Tetramethylhexane
  3. 4-Ethyl-3,4-dimethyloctane
  4. 2,2,3,3-Tetramethylpentane
Ques. 8JEE Main 2024, 9 April (Morning Shift)

Relative stability of the contributing structures is : [figure]

  1. (II) > (I) > (III)
  2. (III) > (II) > (I)
  3. (I) > (III) > (II)
  4. (I) > (II) > (III)
Ques. 9JEE Main 2024, 9 April (Morning Shift)

Correct order of basic strength of Pyrrole, Pyridine and Piperidine is : [figure]

  1. Pyridine > Piperidine > Pyrrole
  2. Pyrrole > Piperidine > Pyridine
  3. Pyrrole > Pyridine > Piperidine
  4. Piperidine > Pyridine > Pyrrole
Ques. 10JEE Main 2024, 9 April (Morning Shift)

How many compounds among the following compounds show inductive, mesomeric as well as hyperconjugation effects? [figure]

Ques. 11JEE Main 2024, 9 April (Evening Shift)

The correct stability order of the following resonance structures of CH3-CH=CH-CHO is [figure]

  1. II > III > I
  2. II > I > III
  3. III > II > I
  4. I > II > III

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