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Classification of Elements and Periodicity in Properties

AIPMT 2010 (Prelims)MCQEasy📈 Topic in 38% papers+4−1
Ques. 1AIPMT 2010 (Prelims)

The correct order of the decreasing ionic radii among the following isoelectronic species is

  1. Ca2+ > K+ > S2- > Cl-
  2. Cl- > S2- > Ca2+ > K+
  3. S2- > Cl- > K+ > Ca2+
  4. K+ > Ca2+ > Cl- > S2-

Answer

(3) S2- > Cl- > K+ > Ca2+

Solution

All four species have 18 electrons (isoelectronic).

As per NCERT, among isoelectronic species, the greater the nuclear charge, the greater the attraction for the electrons and the smaller the ionic radius.

Nuclear charge: S (16) < Cl (17) < K (19) < Ca (20)

∴ Ionic radii: S2- > Cl- > K+ > Ca2+

Answer: (3)

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Ques. 2AIPMT 2010 (Prelims)

Which of the following represents the correct order of increasing electron gain enthalpy with negative sign for the elements O, S, F and Cl ?

  1. Cl < F < O < S
  2. O < S < F < Cl
  3. F < S < O < Cl
  4. S < O < Cl < F
Ques. 3AIPMT 2009

Amongst the elements with following electronic configurations, which one of them may have the highest ionisation energy ?

  1. [Ne] 3s2 3p2
  2. [Ar] 3d10 4s2 4p3
  3. [Ne] 3s2 3p1
  4. [Ne] 3s2 3p3
Ques. 4AIPMT 2007

Identify the correct order of the size of the following:

  1. Ca2+ < K+ < Ar < Cl- < S2-
  2. Ar < Ca2+ < K+ < Cl- < S2-
  3. Ca2+ < Ar < K+ < Cl- < S2-
  4. Ca2+ < K+ < Ar < S2- < Cl-
Ques. 5AIPMT 2007

With which of the following electronic configuration an atom has the lowest ionisation enthalpy?

  1. 1s2 2s2 2p3
  2. 1s2 2s2 2p6 3s1
  3. 1s2 2s2 2p6
  4. 1s2 2s2 2p5
Ques. 6AIPMT 2006

Which of the following is the most basic oxide?

  1. SeO2
  2. Al2O3
  3. Sb2O3
  4. Bi2O3
Ques. 7AIPMT 2005

Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species ?

  1. S < O < Cl < F
  2. Cl < F < S < O
  3. F < Cl < O < S
  4. O < S < F < Cl
Ques. 8AIPMT 2005

A nuclide of an alkaline earth metal undergoes radioactive decay by emission of three -particles in succession. The group of the periodic table to which the resulting daughter element would belong is

  1. Gr. 13
  2. Gr. 17
  3. Gr. 14
  4. Gr. 16
Ques. 9AIPMT 2004

Ionic radii are

  1. inversely proportional to effective nuclear charge
  2. inversely proportional to square of effective nuclear charge
  3. directly proportional to effective nuclear charge
  4. directly proportional to square of effective nuclear charge.
Ques. 10AIPMT 2003

The ions O2-, F-, Na+, Mg2+ and Al3+ are isoelectronic. Their ionic radii show

  1. a significant increase from O2- to Al3+
  2. a significant decrease from O2- to Al3+
  3. an increase from O2- to F- and then decrease from Na+ to Al3+
  4. a decrease from O2- to F- and then increase from Na+ to Al3+
Ques. 11AIPMT 2002

Which of the following is isoelectronic?

  1. CO2, NO2
  2. NO2-, CO2
  3. CN-, CO
  4. SO2, CO2

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