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Classification of Elements and Periodicity in Properties

AIPMT 2007MCQMedium📈 Topic in 38% papers+4−1
Ques. 1AIPMT 2007

Identify the correct order of the size of the following:

  1. Ca2+ < K+ < Ar < Cl- < S2-
  2. Ar < Ca2+ < K+ < Cl- < S2-
  3. Ca2+ < Ar < K+ < Cl- < S2-
  4. Ca2+ < K+ < Ar < S2- < Cl-

Answer

(1) Ca2+ < K+ < Ar < Cl- < S2-

Solution

Ca2+, K+, Ar, Cl- and S2- are isoelectronic (18 electrons each).

As per NCERT, among isoelectronic species, the greater the nuclear charge, the greater is the attraction for the electrons and the smaller is the size.

Nuclear charge: Ca (20) > K (19) > Ar (18) > Cl (17) > S (16)

∴ Size: Ca2+ < K+ < Ar < Cl- < S2-

Answer: (1)

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Ques. 2AIPMT 2007

With which of the following electronic configuration an atom has the lowest ionisation enthalpy?

  1. 1s2 2s2 2p3
  2. 1s2 2s2 2p6 3s1
  3. 1s2 2s2 2p6
  4. 1s2 2s2 2p5
Ques. 3AIPMT 2006

Which of the following is the most basic oxide?

  1. SeO2
  2. Al2O3
  3. Sb2O3
  4. Bi2O3
Ques. 4AIPMT 2005

Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species ?

  1. S < O < Cl < F
  2. Cl < F < S < O
  3. F < Cl < O < S
  4. O < S < F < Cl
Ques. 5AIPMT 2005

A nuclide of an alkaline earth metal undergoes radioactive decay by emission of three -particles in succession. The group of the periodic table to which the resulting daughter element would belong is

  1. Gr. 13
  2. Gr. 17
  3. Gr. 14
  4. Gr. 16
Ques. 6AIPMT 2004

Ionic radii are

  1. inversely proportional to effective nuclear charge
  2. inversely proportional to square of effective nuclear charge
  3. directly proportional to effective nuclear charge
  4. directly proportional to square of effective nuclear charge.
Ques. 7AIPMT 2003

The ions O2-, F-, Na+, Mg2+ and Al3+ are isoelectronic. Their ionic radii show

  1. a significant increase from O2- to Al3+
  2. a significant decrease from O2- to Al3+
  3. an increase from O2- to F- and then decrease from Na+ to Al3+
  4. a decrease from O2- to F- and then increase from Na+ to Al3+
Ques. 8AIPMT 2002

Which of the following is isoelectronic?

  1. CO2, NO2
  2. NO2-, CO2
  3. CN-, CO
  4. SO2, CO2
Ques. 9AIPMT 2002

Which of the following order is wrong?

  1. NH3 < PH3 < AsH3 – acidic
  2. Li < Be < B < C – 1st IP
  3. Al2O3 < MgO < Na2O < K2O – basic
  4. Li+ < Na+ < K+ < Cs+ – ionic radius
Ques. 10AIPMT 2002

An atom has electronic configuration 1s2 2s2 2p6 3s2 3p6 3d3 4s2, you will place it in which group?

  1. fifth
  2. fifteenth
  3. second
  4. third
Ques. 11AIPMT 2001

Correct order of 1st ionization potential among following elements Be, B, C, N, O is

  1. B < Be < C < O < N
  2. B < Be < C < N < O
  3. Be < B < C < N < O
  4. Be < B < C < O < N

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