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Structure of Atom

JEE Main 2025 (Online) 28th January Morning ShiftMCQEasy📈 Topic in 14% papers+4−1
Ques. 1JEE Main 2025, 28 January (Morning Shift)

In a multielectron atom, which of the following orbitals described by three quantum numbers will have same energy in absence of electric and magnetic fields? Choose the correct answer from the options given below:

  1. B and C Only
  2. C and D Only
  3. A and B Only
  4. D and E Only

Answer

(4) D and E Only

Solution

In a multielectron atom the energy of an orbital depends on both n and l (the (n+l) rule); orbitals with the same n and same l (differing only in ml) are degenerate in the absence of electric and magnetic fields.

A: 1s; B: 2s; C: 2p; D: 3d; E: 3d.

2s and 2p (B, C) have different l different energies.

D and E are both 3d orbitals (n = 3, l = 2) same energy.

Answer: (4)

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Ques. 2JEE Main 2025, 28 January (Evening Shift)

Which of the following is/are not correct with respect to energy of atomic orbitals of hydrogen atom? Choose the correct answer from the options given below :

  1. (A) and (B) only
  2. (A) and (C) only
  3. (B) and (D) only
  4. (C) and (D) only
Ques. 3JEE Main 2025, 24 January (Evening Shift)

For hydrogen atom, the orbital/s with lowest energy is/are : Choose the correct answer from the options given below :

  1. A only
  2. B only
  3. B, C and D only
  4. A and E only
Ques. 4JEE Main 2025, 23 January (Morning Shift)

Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H atom is suitable for this? Given : Rydberg constant RH = 105 cm-1, h = 6.6 10-34 J s, c = 3 108 m/s

  1. Lyman series, 1
  2. Balmer series, 2
  3. Paschen series, 5 3
  4. Paschen series, 3
Ques. 5JEE Main 2025, 23 January (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is false but Statement II is true
  4. Statement I is true but Statement II is false
Ques. 6JEE Main 2025, 23 January (Evening Shift)

Given below are two statements about X-ray spectra of elements : In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is false but Statement II is true
  2. Both Statement I and Statement II are true
  3. Statement I is true but Statement II is false
  4. Both Statement I and Statement II are false
Ques. 7JEE Main 2025, 22 January (Morning Shift)

Radius of the first excited state of Helium ion is given as : a0 radius of first stationary state of hydrogen atom.

  1. r = a04
  2. r = 2a0
  3. r = 4a0
  4. r = a02
Ques. 8JEE Main 2025, 22 January (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is false but Statement II is true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Both Statement I and Statement II are true
Ques. 9JEE Main 2025, 22 January (Evening Shift)

Niobium (Nb) and ruthenium (Ru) have “x” and “y” number of electrons in their respective 4 d orbitals. The value of x+y is .

Ques. 10JEE Main 2024, 9 April (Morning Shift)

Compare the energies of following sets of quantum numbers for multielectron system. (A) n = 4, l = 1 (B) n = 4, l = 2 (C) n = 3, l = 1 (D) n = 3, l = 2 (E) n = 4, l = 0 Choose the correct answer from the options given below :

  1. (E) > (C) > (A) > (D) > (B)
  2. (B) > (A) > (C) > (E) > (D)
  3. (C) < (E) < (D) < (A) < (B)
  4. (E) < (C) < (D) < (A) < (B)
Ques. 11JEE Main 2024, 9 April (Evening Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-IV, B-III, C-II, D-I
  2. A-I, B-IV, C-III, D-II
  3. A-III, B-II, C-I, D-IV
  4. A-II, B-I, C-IV, D-III

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