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Equilibrium

AIPMT 2004MCQEasy📈 Topic in 38% papers+4−1
Ques. 1AIPMT 2004

The solubility product of a sparingly soluble salt AX2 is 3.2 10-11. Its solubility (in moles/L) is

  1. 5.6 10-6
  2. 3.1 10-4
  3. 2 10-4
  4. 4 10-4

Answer

(3) 2 10-4

Solution

AX2(s) A2+(aq) + 2X-(aq)

If the solubility is s mol/L, then [ A2+] = s and [X-] = 2s, so

Ksp = s(2s)2 = 4s3

4s3 = 3.2 10-11

s3 = 8 10-12

∴ s = 2 10-4 mol L-1

Answer: (3)

Keep practising — Equilibrium

Ques. 2AIPMT 2004

The rapid change of pH near the stoichiometric point of an acid-base titration is the basis of indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate acid (HIn) and base (In-) forms of the indicator by the expression

  1. [In-][HIn] = pKIn - pH
  2. [HIn][In-] = pKIn - pH
  3. [HIn][In-] = pH - pKIn
  4. [In-][HIn] = pH - pKIn
Ques. 3AIPMT 2003

The equilibrium constants of the following are N2 + 3H2 2NH3; K1 N2 + O2 2NO; K2 H2 + 12O2 H2O; K3 The equilibrium constant (K) of the reaction : 2NH3 + 52O2 2NO + 3H2O will be

  1. K2K33/K1
  2. K2K3/K1
  3. K23K3/K1
  4. K1K33/K2
Ques. 4AIPMT 2003

The reaction quotient (Q) for the reaction N2(g) + 3H2(g) 2NH3(g) is given by Q = [NH3]2[N2][H2]3. The reaction will proceed from right to left if

  1. Q = Kc
  2. Q < Kc
  3. Q > Kc
  4. Q = 0
Ques. 5AIPMT 2003

The solubility product of AgI at 25 C is 1.0 10-16 mol2 L-2. The solubility of AgI in 10-4 N solution of KI at 25 C is approximately (in mol L-1)

  1. 1.0 10-16
  2. 1.0 10-12
  3. 1.0 10-10
  4. 1.0 10-8
Ques. 6AIPMT 2002

Reaction BaO2(s) BaO(s) + O2(g); H = +ve. In equilibrium condition, pressure of O2 depends on

  1. increase mass of BaO2
  2. increase mass of BaO
  3. increase temperature on equilibrium
  4. increase mass of BaO2 and BaO both
Ques. 7AIPMT 2002

Solubility of MX2 type electrolytes is 0.5 10-4 mole/lit., then find out Ksp of electrolytes.

  1. 5 10-12
  2. 25 10-10
  3. 1 10-13
  4. 5 10-13
Ques. 8AIPMT 2002

Which has highest pH?

  1. CH3COOK
  2. Na2CO3
  3. NH4Cl
  4. NaNO3
Ques. 9AIPMT 2002

Solution of 0.1 N NH4OH and 0.1 N NH4Cl has pH 9.25. Then find out pKb of NH4OH

  1. 9.25
  2. 4.75
  3. 3.75
  4. 8.25
Ques. 10AIPMT 2001

In HS-, I-, R-NH2, NH3 order of proton accepting tendency will be

  1. I- > NH3 > R-NH2 > HS-
  2. NH3 > R-NH2 > HS- > I-
  3. R-NH2 > NH3 > HS- > I-
  4. HS- > R-NH2 > NH3 > I-
Ques. 11AIPMT 2001

Ionisation constant of CH3COOH is 1.7 10-5 and concentration of H+ ions is 3.4 10-4. Then find out initial concentration of CH3COOH molecules.

  1. 3.4 10-4
  2. 3.4 10-3
  3. 6.8 10-4
  4. 6.8 10-3

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