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Equilibrium

AIPMT 2002MCQMedium📈 Topic in 25% papers+4−1
Ques. 1AIPMT 2002

Reaction BaO2(s) BaO(s) + O2(g); H = +ve. In equilibrium condition, pressure of O2 depends on

  1. increase mass of BaO2
  2. increase mass of BaO
  3. increase temperature on equilibrium
  4. increase mass of BaO2 and BaO both

Answer

(3) increase temperature on equilibrium

Solution

For this heterogeneous equilibrium, the active masses of the pure solids are taken as constant (unity).

⇒ Kp = pO2

∴ At equilibrium, pO2 is fixed by Kp alone and does not depend on the amounts of BaO2 or BaO.

∵ Kp changes only with temperature, and the reaction is endothermic, increasing the temperature increases Kp and hence pO2.

Answer: (3)

Keep practising — Equilibrium

Ques. 2AIPMT 2002

Solubility of MX2 type electrolytes is 0.5 10-4 mole/lit., then find out Ksp of electrolytes.

  1. 5 10-12
  2. 25 10-10
  3. 1 10-13
  4. 5 10-13
Ques. 3AIPMT 2002

Which has highest pH?

  1. CH3COOK
  2. Na2CO3
  3. NH4Cl
  4. NaNO3
Ques. 4AIPMT 2002

Solution of 0.1 N NH4OH and 0.1 N NH4Cl has pH 9.25. Then find out pKb of NH4OH

  1. 9.25
  2. 4.75
  3. 3.75
  4. 8.25
Ques. 5AIPMT 2001

In HS-, I-, R-NH2, NH3 order of proton accepting tendency will be

  1. I- > NH3 > R-NH2 > HS-
  2. NH3 > R-NH2 > HS- > I-
  3. R-NH2 > NH3 > HS- > I-
  4. HS- > R-NH2 > NH3 > I-
Ques. 6AIPMT 2001

Ionisation constant of CH3COOH is 1.7 10-5 and concentration of H+ ions is 3.4 10-4. Then find out initial concentration of CH3COOH molecules.

  1. 3.4 10-4
  2. 3.4 10-3
  3. 6.8 10-4
  4. 6.8 10-3
Ques. 7AIPMT 2001

Solubility of M2S salt is 3.5 10-6 then find out solubility product.

  1. 1.7 10-6
  2. 1.7 10-16
  3. 1.7 10-18
  4. 1.7 10-12
Ques. 8AIPMT 2001

Correct relation between dissociation constants of a dibasic acid is

  1. Ka1 = Ka2
  2. Ka1 > Ka2
  3. Ka1 < Ka2
  4. Ka1 = 1 Ka2
Ques. 9AIPMT 2000

For any reversible reaction, if we increase concentration of the reactants, then effect on equilibrium constant

  1. depends on amount of concentration
  2. unchanged
  3. decrease
  4. increase
Ques. 10AIPMT 2000

Conjugate acid of NH2- is

  1. NH4OH
  2. NH4+
  3. NH2-
  4. NH3
Ques. 11AIPMT 2000

Which statement is wrong about pH and H+?

  1. pH of neutral water is not zero.
  2. Adding 1 N solution of CH3COOH and 1 N solution of NaOH, pH will be seven.
  3. [H+] of dilute and hot H2SO4 is more than concentrated and cold H2SO4
  4. Mixing solution of CH3COOH and HCl. pH will be less than 7.

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