Amines

Which among the following react with Hinsberg's reagent? Choose the correct answer from the options given below :

1. A, C and E only
2. A, B and E only
3. C and D only
4. B and D only

Consider the following sequence of reactions to produce major product (A) [figure] Molar mass of product (A) is g mol-1. (Given molar mass in g mol-1 of C : 12, H : 1, O : 16, Br : 80, N : 14, P : 31)

Consider the following sequence of reactions. [figure] Total number of sp3 hybridised carbon atoms in the major product C formed is .

The products formed in the following reaction sequence are : [figure]

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Consider the following sequence of reactions : [figure] Molar mass of the product formed (A) is g mol-1.

Match the Compounds (List - I) with the appropriate Catalyst/ Reagents (List - II) for their reduction into corresponding amines. Choose the correct answer from the options given below :

1. A-II, B-IV, C-III, D-I
2. A-III, B-IV, C-II, D-I
3. A-III, B-II, C-IV, D-I
4. A-II, B-I, C-III, D-IV

If 279 g of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be g. (nearest integer) (consider complete conversion).

Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is . [figure]

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is false but Statement II is true
2. Both Statement I and Statement II are true
3. Both Statement I and Statement II are false
4. Statement I is true but Statement II is false

9.3 g of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is g. (nearest integer)