Amines

Consider the following sequence of reactions : [figure] Molar mass of the product formed (A) is g mol-1.

Match the Compounds (List - I) with the appropriate Catalyst/ Reagents (List - II) for their reduction into corresponding amines. Choose the correct answer from the options given below :

1. A-II, B-IV, C-III, D-I
2. A-III, B-IV, C-II, D-I
3. A-III, B-II, C-IV, D-I
4. A-II, B-I, C-III, D-IV

If 279 g of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be g. (nearest integer) (consider complete conversion).

Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is . [figure]

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is false but Statement II is true
2. Both Statement I and Statement II are true
3. Both Statement I and Statement II are false
4. Statement I is true but Statement II is false

9.3 g of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is g. (nearest integer)

An amine (X) is prepared by ammonolysis of benzyl chloride. On adding p-toluenesulphonyl chloride to it the solution remains clear. Molar mass of the amine (X) formed is g mol-1. (Given molar mass in g mol-1 C : 12, H : 1, O : 16, N : 14)

9.3 g of pure aniline is treated with bromine water at room temperature to give a white precipitate of the product 'P'. The mass of product 'P' obtained is 26.4 g. The percentage yield is %.

X g of ethanamine was subjected to reaction with NaNO2/HCl followed by hydrolysis to liberate N2 and HCl. The HCl generated was completely neutralised by 0.2 moles of NaOH. X is g.

Xg of ethylamine is subjected to reaction with NaNO2/HCl followed by water; evolved dinitrogen gas which occupied 2.24 L volume at STP. X is 10-1 g.