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Classification of Elements and Periodicity in Properties

NEET 2013 (Karnataka)MCQMedium📈 Topic in 12% papers+4−1
Ques. 1NEET 2013 (Karnataka)

Which one of the following arrangements represents the correct order of least negative to most negative electron gain enthalpy for C, Ca, Al, F and O?

  1. Al < Ca < O < C < F
  2. Al < O < C < Ca < F
  3. C < F < O < Al < Ca
  4. Ca < Al < C < O < F

Answer

(4) Ca < Al < C < O < F

Solution

Ca has a filled 4s subshell, so the added electron enters a higher-energy 4p orbital ⇒ its electron gain enthalpy is nearly zero (least negative).

Al ( -44 kJ mol-1) < C (-122) < O (-141) < F (-328 kJ mol-1)

∵ Electron gain enthalpy becomes more negative across a period as the effective nuclear charge increases.

∴ Order: Ca < Al < C < O < F

Answer: (4)

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Ques. 2AIPMT 2012 (Prelims)

Identify the wrong statement in the following.

  1. Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius.
  2. Amongst isoelectronic species, greater the negative charge on the anion, larger is the ionic radius.
  3. Atomic radius of the elements increases as one moves down the first group of the periodic table.
  4. Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of the periodic table.
Ques. 3AIPMT 2011 (Mains)

What is the value of electron gain enthalpy of Na+ if IE1 of Na = 5.1 eV?

  1. -5.1 eV
  2. -10.2 eV
  3. +2.55 eV
  4. +10.2 eV
Ques. 4AIPMT 2011 (Mains)

Which of the following oxide is amphoteric?

  1. SnO2
  2. CaO
  3. SiO2
  4. CO2
Ques. 5AIPMT 2010 (Mains)

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is

  1. Mg < Ca < Cl < P
  2. Cl < P < Mg < Ca
  3. P < Cl < Ca < Mg
  4. Ca < Mg < P < Cl
Ques. 6AIPMT 2010 (Mains)

Among the following which one has the highest cation to anion size ratio?

  1. CsI
  2. CsF
  3. LiF
  4. NaF
Ques. 7AIPMT 2010 (Prelims)

The correct order of the decreasing ionic radii among the following isoelectronic species is

  1. Ca2+ > K+ > S2- > Cl-
  2. Cl- > S2- > Ca2+ > K+
  3. S2- > Cl- > K+ > Ca2+
  4. K+ > Ca2+ > Cl- > S2-
Ques. 8AIPMT 2010 (Prelims)

Which of the following represents the correct order of increasing electron gain enthalpy with negative sign for the elements O, S, F and Cl ?

  1. Cl < F < O < S
  2. O < S < F < Cl
  3. F < S < O < Cl
  4. S < O < Cl < F
Ques. 9AIPMT 2009

Amongst the elements with following electronic configurations, which one of them may have the highest ionisation energy ?

  1. [Ne] 3s2 3p2
  2. [Ar] 3d10 4s2 4p3
  3. [Ne] 3s2 3p1
  4. [Ne] 3s2 3p3
Ques. 10AIPMT 2007

Identify the correct order of the size of the following:

  1. Ca2+ < K+ < Ar < Cl- < S2-
  2. Ar < Ca2+ < K+ < Cl- < S2-
  3. Ca2+ < Ar < K+ < Cl- < S2-
  4. Ca2+ < K+ < Ar < S2- < Cl-
Ques. 11AIPMT 2007

With which of the following electronic configuration an atom has the lowest ionisation enthalpy?

  1. 1s2 2s2 2p3
  2. 1s2 2s2 2p6 3s1
  3. 1s2 2s2 2p6
  4. 1s2 2s2 2p5

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