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Amines

AIPMT 2010 (Prelims)MCQEasy📈 Topic in 75% papers+4−1
Ques. 1AIPMT 2010 (Prelims)

Acetamide is treated with the following reagents separately. Which one of these would yield methyl amine?

  1. NaOH/Br2
  2. Sodalime
  3. Hot conc. H2SO4
  4. PCl5

Answer

(1) NaOH/Br2

Solution

Hoffmann bromamide degradation: an amide with Br2 and NaOH gives a primary amine with one carbon atom less.

CH3CONH2 + Br2 + 4NaOH CH3NH2 + Na2CO3 + 2NaBr + 2H2O

Answer: (1)

Keep practising — Amines

Ques. 2AIPMT 2010 (Prelims)

Which of the following statements about primary amines is false?

  1. Alkyl amines are stronger bases than aryl amines.
  2. Alkyl amines react with nitrous acid to produce alcohols.
  3. Aryl amines react with nitrous acid to produce phenols.
  4. Alkyl amines are stronger bases than ammonia.
Ques. 3AIPMT 2010 (Prelims)

Aniline in a set of the following reactions yielded a coloured product Y. [figure] The structure of 'Y' would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4AIPMT 2009

Predict the product. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5AIPMT 2008

In a reaction of aniline a coloured product C was obtained. [figure] The structure of C would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6AIPMT 2007

Which one of the following on reduction with lithium aluminium hydride yields a secondary amine?

  1. Methyl isocyanide
  2. Acetamide
  3. Methyl cyanide
  4. Nitroethane
Ques. 7AIPMT 2006

In a set of reactions propionic acid yielded a compound D. CH3CH2COOH SOCl2 B NH3 C [Br2]KOH D The structure of D would be

  1. CH3CH2NH2
  2. CH3CH2CH2NH2
  3. CH3CH2CONH2
  4. CH3CH2NHCH3
Ques. 8AIPMT 2006

Which of the following is more basic than aniline?

  1. Benzylamine
  2. Diphenylamine
  3. Triphenylamine
  4. p-Nitroaniline
Ques. 9AIPMT 2005

The major organic product formed from the following reaction : [figure] is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10AIPMT 2005

Electrolytic reduction of nitrobenzene in weakly acidic medium gives

  1. N-phenylhydroxylamine
  2. nitrosobenzene
  3. aniline
  4. p-hydroxyaniline
Ques. 11AIPMT 2005

Aniline in a set of reactions yielded a product D. [figure] The structure of the product D would be

  1. C6H5NHOH
  2. C6H5NHCH2CH3
  3. C6H5CH2NH2
  4. C6H5CH2OH

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