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Amines

AIPMT 2009MCQMedium📈 Topic in 62% papers+4−1
Ques. 1AIPMT 2009

Predict the product. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(4) [figure]

Solution

As per NCERT, secondary amines react with nitrous acid (NaNO2 + HCl) to give N-nitrosoamines (yellow oily compounds).

NaNO2 + HCl HNO2 + NaCl

C6H5NHCH3 + HO-N=O C6H5N(CH3)-N=O + H2O

The product is N-methyl-N-nitrosoaniline.

Answer: (4)

Keep practising — Amines

Ques. 2AIPMT 2008

In a reaction of aniline a coloured product C was obtained. [figure] The structure of C would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 3AIPMT 2007

Which one of the following on reduction with lithium aluminium hydride yields a secondary amine?

  1. Methyl isocyanide
  2. Acetamide
  3. Methyl cyanide
  4. Nitroethane
Ques. 4AIPMT 2006

In a set of reactions propionic acid yielded a compound D. CH3CH2COOH SOCl2 B NH3 C [Br2]KOH D The structure of D would be

  1. CH3CH2NH2
  2. CH3CH2CH2NH2
  3. CH3CH2CONH2
  4. CH3CH2NHCH3
Ques. 5AIPMT 2006

Which of the following is more basic than aniline?

  1. Benzylamine
  2. Diphenylamine
  3. Triphenylamine
  4. p-Nitroaniline
Ques. 6AIPMT 2005

The major organic product formed from the following reaction : [figure] is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 7AIPMT 2005

Electrolytic reduction of nitrobenzene in weakly acidic medium gives

  1. N-phenylhydroxylamine
  2. nitrosobenzene
  3. aniline
  4. p-hydroxyaniline
Ques. 8AIPMT 2005

Aniline in a set of reactions yielded a product D. [figure] The structure of the product D would be

  1. C6H5NHOH
  2. C6H5NHCH2CH3
  3. C6H5CH2NH2
  4. C6H5CH2OH
Ques. 9AIPMT 2004

In a reaction of aniline a coloured product C was obtained. [figure] The structure of C would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10AIPMT 2003

The final product C, obtained in this reaction [figure] would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 11AIPMT 2002

CH3CH2Cl NaCN X Ni/H2 Y acetic anhydride Z Z in the above reaction sequence is

  1. CH3CH2CH2NHCOCH3
  2. CH3CH2CH2NH2
  3. CH3CH2CH2CONHCH3
  4. CH3CH2CH2CONHCOCH3

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