Ques. 1JEE Main 2025, 22 January (Morning Shift)
Which of the following electrolyte can be used to obtain H2S2O8 by the process of electrolysis ?
- Concentrated solution of sulphuric acid
- Dilute solution of sodium sulphate.
- Acidified dilute solution of sodium sulphate.
- Dilute solution of sulphuric acid
Answer
(1) Concentrated solution of sulphuric acid
Solution
Anode: 2HSO4- H2S2O8 + 2e-, cathode: 2H+ + 2e- H2
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HSO4- must be plentiful concentrated H2SO4; in dilute solutions water is oxidised to O2 instead.
Answer: (1)