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Hydrocarbons

JEE Main 2026 (Online) 2nd April Evening ShiftMCQEasy📈 Topic in 18% papers+4−1
Ques. 1JEE Main 2026, 2 April (Evening Shift)

The compound (X) on (i) on heating in the presence of anhydrous AlCl3 and HCl gas gives 2,4-dimethyl pentane (ii) aromatization gives toluene and (iii) cyclisation gives methyl cyclohexane The correct name of compound (X) is:

  1. Hept-2-ene
  2. Hept-1,3,5-triene
  3. Heptane
  4. Hept-2,4,6-triene

Answer

(3) Heptane

Solution

(i) Isomerisation: n-alkanes on heating with anhydrous AlCl3 and HCl gas give branched alkanes. 2,4-Dimethylpentane is C7H16 ⇒ X is the saturated isomer n-heptane.

(ii) Aromatisation (NCERT): n-heptane [10-20 atm]Cr2O3/V2O5/Mo2O3, 773 K toluene

(iii) Cyclisation of n-heptane gives methylcyclohexane (the first step of aromatisation).

∴ X = heptane.

Answer: (3)

Keep practising — Hydrocarbons

Ques. 2JEE Main 2026, 28 January (Morning Shift)

Given below are two statements for the following reaction sequence. [figure] In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is true but Statement II is false
  2. Both Statement I and Statement II are true
  3. Statement I is false but Statement II is true
  4. Both Statement I and Statement II are false
Ques. 3JEE Main 2026, 28 January (Morning Shift)

Ph-CH=CH2 [HBr](PhCOO)2 Product Consider the above reaction Identify the correct statements. Choose the correct answer from the options given below :

  1. A & E Only
  2. A, B & D Only
  3. A, C & E Only
  4. C, D & E Only
Ques. 4JEE Main 2026, 28 January (Evening Shift)

The reactions which produce alcohol as the product are : Choose the correct answer from the options given below :

  1. B, D and E Only
  2. A and D Only
  3. A, C and E Only
  4. C and D Only
Ques. 5JEE Main 2026, 23 January (Morning Shift)

Consider the following compounds : [figure] Arrange these compounds in the increasing order of reactivity with nitrating mixture.

  1. c < b < a
  2. b < c < a
  3. c < a < b
  4. b < a < c
Ques. 6JEE Main 2026, 23 January (Morning Shift)

But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) Na/ liq. NH3 to give the products X and Y respectively. [figure] Identify the incorrect statements. Choose the correct answer from the options given below :

  1. B and D Only
  2. A and C Only
  3. A and B Only
  4. B and C Only
Ques. 7JEE Main 2026, 23 January (Evening Shift)

[figure] Identify (P)

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 8JEE Main 2026, 22 January (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below

  1. Statement I is incorrect but Statement II is correct
  2. Both Statement I and Statement II are correct
  3. Both Statement I and Statement II are incorrect
  4. Statement I is correct but Statement II is incorrect
Ques. 9JEE Main 2026, 22 January (Morning Shift)

The cycloalkene (X) on bromination consumes one mole of bromine per mole of (X) and gives the product (Y) in which C : Br ratio is 3:1. The percentage of bromine in the product (Y) is %. (Nearest integer) (Given : molar mass in g mol-1 H : 1, C : 12, O : 16, Br : 80)

Ques. 10JEE Main 2026, 22 January (Evening Shift)

Consider the following reaction : [figure] The product Y formed is :

  1. 2-methylhex-3-yne
  2. 5-methylhex-2-yne
  3. Isopropylbut-1-yne
  4. 2-methylhex-2-yne
Ques. 11JEE Main 2026, 22 January (Evening Shift)

The dibromo compound [P] (molecular formula: C9H10Br2) when heated with excess sodamide followed by treatment with dilute HCl gives [Q]. On warming [Q] with mercuric sulphate and dilute sulphuric acid yields [R] which gives positive Iodoform test but negative Tollens' test. The compound [P] is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

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All JEE Main Chemistry chapters
Physical ChemistrySome Basic Concepts of ChemistryStructure of AtomStates of MatterThermodynamicsEquilibriumRedox ReactionsSolutionsElectrochemistryChemical Kinetics
Inorganic ChemistryClassification of Elements and Periodicity in PropertiesChemical Bonding and Molecular Structurep-Block Elements (Group 13 & 14)p-Block Elements (Group 15–18)d- and f-Block ElementsCoordination Compounds
Organic ChemistryOrganic Chemistry – Some Basic Principles and TechniquesIsomerismHydrocarbonsHaloalkanes and HaloarenesAlcohols, Phenols and EthersAldehydes, Ketones and Carboxylic AcidsAminesBiomoleculesPrinciples Related to Practical Chemistry