Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
- Both Statement I and Statement II are false
- Statement I is false but Statement II is true
- Statement I is true but Statement II is false
- Both Statement I and Statement II are true
Answer
(4) Both Statement I and Statement II are true
Solution
Statement I: the first ionization enthalpies ( kJ mol-1) are C 1086, N 1402, O 1314 and F 1681.
N has the extra-stable half-filled 2p3 configuration, its ionization enthalpy is higher than that of O, so the order is C < O < N < F and Statement I is true.
Statement II: the electron gain enthalpies ( kJ mol-1) are O −141, S −200, Se −195, Te −190 and Po −174.
O is very small, the added electron enters the compact 2p subshell and faces strong inter-electronic repulsion, so the electron gain enthalpy of O is less negative than that of S; down the group from S it becomes less negative.
Thus the order of magnitude is S > Se > Te > Po > O, and Statement II is true.
Answer: (4)