Solutions

Which of the following is dependent on temperature?

1. Molarity
2. Mole fraction
3. Weight percentage
4. Molality

Which of the following statements about the composition of the vapour over an ideal 1 : 1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at 25 . (Given, vapour pressure data at 25 , benzene = 12.8 kPa, toluene = 3.85 kPa)

1. The vapour will contain equal amounts of benzene and toluene.
2. Not enough information is given to make a prediction.
3. The vapour will contain a higher percentage of benzene.
4. The vapour will contain a higher percentage of toluene

At 100 the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be

1. 102
2. 103
3. 101
4. 100

The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is

1. 0
2. 1
3. 2
4. 3

Which one of the following is incorrect for ideal solution?

1. Hmix = 0
2. Umix = 0
3. P = Pobs - Pcalculated by Raoult's law = 0
4. Gmix = 0

What is the mole fraction of the solute in a 1.00 m aqueous solution?

1. 1.770
2. 0.0354
3. 0.0177
4. 0.177

The boiling point of 0.2 mol kg-1 solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in this case?

1. Molecular mass of X is less than the molecular mass of Y.
2. Y is undergoing dissociation in water while X undergoes no change.
3. X is undergoing dissociation in water.
4. Molecular mass of X is greater than the molecular mass of Y.

Which one of the following electrolytes has the same value of van't Hoff factor (i) as that of Al2(SO4)3 (if all are 100% ionised)?

1. Al(NO3)3
2. K4[Fe(CN)6]
3. K2SO4
4. K3[Fe(CN)6]

Which of them is not equal to zero for an ideal solution?

1. Vmix
2. P = Pobserved - PRaoult
3. Hmix
4. Smix

Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression?

1. KCl
2. C6H12O6
3. Al2(SO4)3
4. K2SO4