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Isomerism

JEE Main 2024 (Online) 9th April Evening ShiftMCQMedium📈 Topic in 14% papers+4−1
Ques. 1JEE Main 2024, 9 April (Evening Shift)

Total number of stereo isomers possible for the given structure : [figure]

  1. 4
  2. 2
  3. 8
  4. 3

Answer

(3) 8

Solution

[figure]

Double bond a: each carbon has two different groups (CH3/Br and H/CH2), so it shows geometrical isomerism.

Double bond b: each carbon also has two different groups, so it shows geometrical isomerism too.

C* carries H, Br and two different carbon chains, so it is a chiral centre.

So there are 3 stereogenic units in an unsymmetrical molecule, hence

number of stereoisomers = 2n = 23 = 8

Answer: (3)

Keep practising — Isomerism

Ques. 2JEE Main 2024, 8 April (Morning Shift)

The number of optical isomers in following compound is : . [figure]

Ques. 3JEE Main 2024, 8 April (Evening Shift)

The number of optically active compounds from the following is . [figure] CH3-CH2-CH2-CH2-OH, CH3-CH2- Cl |CH-CH3, CH3-CH2-CH2-CH2-Cl, (CH3)2CH-CH2-CH2-Cl

Ques. 4JEE Main 2024, 6 April (Morning Shift)

Which of the following is metamer of the given compound (X) ? [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5JEE Main 2024, 6 April (Evening Shift)

The incorrect statement regarding the geometrical isomers of 2-butene is :

  1. cis-2-butene and trans-2-butene are not interconvertible at room temperature.
  2. trans-2-butene is more stable than cis-2-butene.
  3. cis-2-butene has less dipole moment than trans-2-butene.
  4. cis-2-butene and trans-2-butene are stereoisomers.
Ques. 6JEE Main 2024, 5 April (Morning Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the correct answer from the options given below :

  1. (A) is true but (R) is false
  2. (A) is false but (R) is true
  3. Both (A) and (R) are true and (R) is the correct explanation of (A)
  4. Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
Ques. 7JEE Main 2024, 5 April (Evening Shift)

Match List - I with List - II. Choose the correct answer from the options given below :

  1. (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
  2. (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
  3. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  4. (A)-(I), (B)-(III), (C)-(IV), (D)-(II)
Ques. 8JEE Main 2024, 4 April (Morning Shift)

The number of different chain isomers for C7H16 is .

Ques. 9JEE Main 2024, 1 February (Morning Shift)

Number of optical isomers possible for 2-chlorobutane .

Ques. 10JEE Main 2024, 1 February (Evening Shift)

Total number of isomeric compounds (including stereoisomers) formed by monochlorination of 2-methylbutane is .

Ques. 11JEE Main 2024, 30 January (Evening Shift)

Number of geometrical isomers possible for the given structure is/are . [figure]

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