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Isomerism

AIPMT 2015MCQEasy📈 Topic in 25% papers+4−1
Ques. 1AIPMT 2015

The number of structural isomers possible from the molecular formula C3H9N is

  1. 5
  2. 2
  3. 3
  4. 4

Answer

(4) 4

Solution

C3H9N is a saturated amine. Possible structures:

1° amines: CH3CH2CH2NH2 (propan-1-amine), (CH3)2CHNH2 (propan-2-amine)

2° amine: CH3NHCH2CH3 (N-methylethanamine)

3° amine: (CH3)3N (N,N-dimethylmethanamine)

∴ Number of structural isomers = 4

Answer: (4)

Keep practising — Isomerism

Ques. 2AIPMT 2015 (Cancelled)

Given : [figure] Which of the given compounds can exhibit tautomerism?

  1. II and III
  2. I, II and III
  3. I and II
  4. I and III
Ques. 3AIPMT 2014

Which of the following compounds will undergo racemisation when solution of KOH hydrolyses? [figure]

  1. (i) and (ii)
  2. (ii) and (iv)
  3. (iv)
  4. (i) and (iv)
Ques. 4NEET 2013

The order of stability of the following tautomeric compounds is [figure]

  1. II > I > III
  2. II > III > I
  3. I > II > III
  4. III > II > I
Ques. 5NEET 2013 (Karnataka)

Given: [figure] I and II are

  1. identical
  2. a pair of conformers
  3. a pair of geometrical isomers
  4. a pair of optical isomers
Ques. 6NEET 2013 (Karnataka)

Number of isomeric alcohols of molecular formula C6H14O which give positive iodoform test is

  1. three
  2. four
  3. five
  4. two
Ques. 7AIPMT 2012 (Prelims)

Which of the following acids does not exhibit optical isomerism?

  1. Maleic acid
  2. -amino acids
  3. Lactic acid
  4. Tartaric acid
Ques. 8AIPMT 2011 (Mains)

The IUPAC name of the following compound is [figure]

  1. trans-2-chloro-3-iodo-2-pentene
  2. cis-3-iodo-4-chloro-3-pentene
  3. trans-3-iodo-4-chloro-3-pentene
  4. cis-2-chloro-3-iodo-2-pentene
Ques. 9AIPMT 2010 (Mains)

Which of the following conformers for ethylene glycol is most stable?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10AIPMT 2010 (Prelims)

In the following the most stable conformation of n-butane is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 11AIPMT 2009

Which of the following compounds will exhibit cis-trans (geometrical) isomerism?

  1. Butanol
  2. 2-Butyne
  3. 2-Butanol
  4. 2-Butene

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