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Chemical Bonding and Molecular Structure

AIPMT 2002MCQEasyNot asked in last 5 yrs+4−1
Ques. 1AIPMT 2002

Which of the following has p - d bonding?

  1. NO3-
  2. SO32-
  3. BO33-
  4. CO32-

Answer

(2) SO32-

Solution

p - d bonding needs a central atom with vacant d orbitals, i.e. an element of the third period or beyond.

N, B and C belong to the second period and have no d orbitals, so NO3-, BO33- and CO32- can form only p - p bonds.

In SO32-, however, S (third period) uses its 3d orbital to form the S=O π bond with a 2p orbital of O.

∴ SO32- has p - d bonding.

Answer: (2)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2AIPMT 2002

In NO3- ion number of bond pair and lone pair of electrons on nitrogen atom are

  1. 2, 2
  2. 3, 1
  3. 1, 3
  4. 4, 0
Ques. 3AIPMT 2001

Main axis of a diatomic molecule is z, atomic orbitals px and py overlap to form which of the following orbitals.

  1. molecular orbital
  2. molecular orbital
  3. molecular orbital
  4. No bond will form
Ques. 4AIPMT 2001

Which of the following two are isostructural?

  1. XeF2, IF2-
  2. NH3, BF3
  3. CO32-, SO32-
  4. PCl5, ICl5
Ques. 5AIPMT 2001

In which of the following bond angle is maximum ?

  1. NH3
  2. NH4+
  3. PCl3
  4. SCl2
Ques. 6AIPMT 2001

In X-H Y, X and Y both are electronegative elements. Then

  1. electron density on X will increase and on H will decrease
  2. in both electron density will increase
  3. in both electron density will decrease
  4. on X electron density will decrease and on H will increase.
Ques. 7AIPMT 2000

d - p bond present in

  1. CO32-
  2. PO43-
  3. NO3-
  4. NO2-
Ques. 8AIPMT 2000

Right order of dissociation energy N2 and N2+ is

  1. N2 > N2+
  2. N2 = N2+
  3. N2+ > N2
  4. none
Ques. 9AIPMT 2000

Which species does not exhibit paramagnetism?

  1. N2+
  2. O2-
  3. CO
  4. NO
Ques. 10AIPMT 2000

Which compound forms linear polymer due to H-bond?

  1. H2O
  2. NH3
  3. HF
  4. HCl
Out of syllabus

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