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Chemical Bonding and Molecular Structure

AIPMT 2001MCQEasy📈 Topic in 62% papers+4−1
Ques. 1AIPMT 2001

Main axis of a diatomic molecule is z, atomic orbitals px and py overlap to form which of the following orbitals.

  1. molecular orbital
  2. molecular orbital
  3. molecular orbital
  4. No bond will form

Answer

(1) molecular orbital

Solution

∵ The internuclear (molecular) axis is the z-axis, the pz orbitals overlap head-on (along the axis) and form molecular orbitals.

The px and py orbitals are perpendicular to the axis, so they overlap sideways (lateral overlap): px with px and py with py.

As per NCERT, sideways overlap of p orbitals gives (bonding) and * (antibonding) molecular orbitals.

∴ px and py form molecular orbitals.

Answer: (1)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2AIPMT 2001

Which of the following two are isostructural?

  1. XeF2, IF2-
  2. NH3, BF3
  3. CO32-, SO32-
  4. PCl5, ICl5
Ques. 3AIPMT 2001

In which of the following bond angle is maximum ?

  1. NH3
  2. NH4+
  3. PCl3
  4. SCl2
Ques. 4AIPMT 2001

In X-H Y, X and Y both are electronegative elements. Then

  1. electron density on X will increase and on H will decrease
  2. in both electron density will increase
  3. in both electron density will decrease
  4. on X electron density will decrease and on H will increase.
Ques. 5AIPMT 2000

d - p bond present in

  1. CO32-
  2. PO43-
  3. NO3-
  4. NO2-
Ques. 6AIPMT 2000

Right order of dissociation energy N2 and N2+ is

  1. N2 > N2+
  2. N2 = N2+
  3. N2+ > N2
  4. none
Ques. 7AIPMT 2000

Which species does not exhibit paramagnetism?

  1. N2+
  2. O2-
  3. CO
  4. NO
Ques. 8AIPMT 2000

Which compound forms linear polymer due to H-bond?

  1. H2O
  2. NH3
  3. HF
  4. HCl
Out of syllabus

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