Redox Reactions

500 mL of 1.2 M KI solution is mixed with 500 mL of 0.2 M KMnO4 solution in basic medium. The liberated iodine was titrated with standard 0.1 M Na2S2O3 solution in the presence of starch indicator till the blue color disappeared. The volume (in L) of Na2S2O3 consumed is . (Nearest integer)

X and Y are the number of electrons involved, respectively during the oxidation of I- to I2 and S2- to S by acidified K2Cr2O7. The value of X + Y is .

200 cc of x 10-3 M potassium dichromate is required to oxidise 750 cc of 0.6 M Mohr's salt solution in acidic medium. Here x = .

Match the List-I with List-II Choose the correct answer from the options given below:

1. A-III, B-IV, C-I, D-II
2. A-IV, B-I, C-II, D-III
3. A-II, B-III, C-I, D-IV
4. A-II, B-III, C-IV, D-I

The species which does not undergo disproportionation reaction is :

1. ClO4-
2. ClO3-
3. ClO-
4. ClO2-

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

1. Statement I is correct but Statement II is incorrect
2. Both Statement I and Statement II are correct
3. Statement I is incorrect but Statement II is correct
4. Both Statement I and Statement II are incorrect

Thiosulphate reacts differently with iodine and bromine in the reactions given below: 2S2O32- + I2 S4O62- + 2I- S2O32- + 5Br2 + 5H2O 2SO42- + 4Br- + 10H+ Which of the following statements justifies the above dual behaviour of thiosulphate?

1. Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions
2. Bromine is a weaker oxidant than iodine
3. Bromine is a stronger oxidant than iodine
4. Bromine undergoes oxidation and iodine undergoes reduction in these reactions

Match List I with List II. Choose the correct answer from the options given below :

1. A-IV, B-I, C-II, D-III
2. A-I, B-II, C-III, D-IV
3. A-II, B-III, C-IV, D-I
4. A-III, B-II, C-I, D-IV

Only 2 mL of KMnO4 solution of unknown molarity is required to reach the end point of a titration of 20 mL of oxalic acid (2M) in acidic medium. The molarity of KMnO4 solution should be M.

Which of the following reactions are disproportionation reactions? Choose the correct answer from the options given below :

1. (A), (B)
2. (A), (D)
3. (B), (C), (D)
4. (A), (B), (C)