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Hydrocarbons

NEET 2016 (Phase 2)MCQMedium📈 Topic in 12% papers+4−1
Ques. 1NEET 2016 (Phase 2)

In the given reaction, [figure] the product P is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(3) [figure]

Solution

HF protonates cyclohexene ⇒ cyclohexyl carbocation (electrophile).

The carbocation attacks benzene (Friedel–Crafts alkylation) and loss of H+ gives cyclohexylbenzene.

C6H6 + C6H10 [0 C]HF C6H5-C6H11

HF only supplies H+ (the catalyst), so F is not present in the product.

Answer: (3)

Keep practising — Hydrocarbons

Ques. 2NEET 2016 (Phase 2)

The compound that will react most readily with gaseous bromine has the formula

  1. C3H6
  2. C2H2
  3. C4H10
  4. C2H4
Ques. 3AIPMT 2015

In the reaction with HCl, an alkene reacts in accordance with the Markovnikov's rule to give a product 1-chloro-1-methylcyclohexane. The possible alkene is

  1. [figure] (A)
  2. [figure] (B)
  3. (A) and (B)
  4. [figure]
Ques. 4AIPMT 2015

2,3-Dimethyl-2-butene can be prepared by heating which of the following compounds with a strong acid?

  1. (CH3)3CCH=CH2
  2. (CH3)2C=CHCH2CH3
  3. (CH3)2CHCH2CH=CH2
  4. (CH3)2CH- CH3 |CH-CH=CH2
Ques. 5AIPMT 2015

The oxidation of benzene by V2O5 in the presence of air produces

  1. maleic anhydride
  2. benzoic acid
  3. benzaldehyde
  4. benzoic anhydride.
Ques. 6AIPMT 2015 (Cancelled)

A single compound of the structure, [figure] is obtainable from ozonolysis of which of the following cyclic compounds?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 7AIPMT 2015 (Cancelled)

The reaction of C6H5CH=CHCH3 with HBr produces

  1. C6H5CH2CH2CH2Br
  2. [figure]
  3. C6H5 Br |CHCH2CH3
  4. C6H5CH2 Br |CHCH3
Ques. 8AIPMT 2014

What products are formed when the following compound is treated with Br2 in the presence of FeBr3? [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 9NEET 2013

Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating ?

  1. -COOH
  2. -NO2
  3. -C N
  4. -SO3H
Ques. 10NEET 2013

Which of the following compounds will not undergo Friedel-Crafts reaction easily?

  1. Nitrobenzene
  2. Toluene
  3. Cumene
  4. Xylene
Ques. 11NEET 2013

Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-100 C forms which one of the following products?

  1. 1, 4-Dinitrobenzene
  2. 1, 2, 4 - Trinitrobenzene
  3. 1, 2-Dinitrobenzene
  4. 1, 3-Dinitrobenzene

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