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p-Block Elements (Group 15–18)

JEE Main 2025 (Online) 28th January Evening ShiftNumericalMedium📈 Topic in 27% papers+4
Ques. 1JEE Main 2025, 28 January (Evening Shift)

A group 15 element forms d - d bond with transition metals. It also forms a hydride, which is the strongest base among the hydrides of other group members that form d - d bond. The atomic number of the element is .

Answer

15

Solution

As per NCERT, phosphorus and arsenic can form d - d bonds with transition metals when their compounds like P(C2H5)3 and As(C6H5)3 act as ligands. Nitrogen cannot (no d orbitals in its valence shell).

Basic strength of group 15 hydrides decreases down the group:

NH3 > PH3 > AsH3 > SbH3 BiH3

Among the elements forming d - d bonds (P, As), the hydride PH3 is the strongest base.

The element is phosphorus, atomic number 15.

Answer: 15

Keep practising — p-Block Elements (Group 15–18)

Ques. 2JEE Main 2025, 24 January (Morning Shift)

The large difference between the melting and boiling points of oxygen and sulphur may be explained on the basis of

  1. Atomicity
  2. Electron gain enthalpy
  3. Atomic size
  4. Electronegativity
Ques. 3JEE Main 2025, 23 January (Morning Shift)

The incorrect statement among the following is

  1. PH3 shows lower proton affinity than NH3.
  2. SO2 can act as an oxidizing agent, but not as a reducing agent.
  3. NO2 can dimerise easily.
  4. PF3 exists but NF5 does not.
Ques. 4JEE Main 2025, 22 January (Evening Shift)

The maximum covalency of a non-metallic group 15 element ' E ' with weakest E-E bond is :

  1. 5
  2. 3
  3. 4
  4. 6
Ques. 5JEE Main 2024, 9 April (Morning Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  2. (A) is correct but (R) is not correct
  3. (A) is not correct but (R) is correct
  4. Both (A) and (R) are correct and (R) is the correct explanation of (A)
Ques. 6JEE Main 2024, 9 April (Morning Shift)

On reaction of Lead Sulphide with dilute nitric acid which of the following is not formed?

  1. Sulphur
  2. Nitric oxide
  3. Lead nitrate
  4. Nitrous oxide
Ques. 7JEE Main 2024, 9 April (Evening Shift)

Number of oxygen atoms present in chemical formula of fuming sulphuric acid is .

Ques. 8JEE Main 2024, 8 April (Morning Shift)

Among the following halogens F2, Cl2, Br2 and I2 Which can undergo disproportionation reactions?

  1. F2 and Cl2
  2. Cl2, Br2 and I2
  3. Only I2
  4. F2, Cl2 and Br2
Ques. 9JEE Main 2024, 8 April (Evening Shift)

Identify the incorrect statements about group 15 elements : Choose the correct answer from the options given below :

  1. (A), (C), (E) only
  2. (D) and (E) only
  3. (A), (B), (D) only
  4. (B), (D), (E) only
Ques. 10JEE Main 2024, 1 February (Morning Shift)

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  2. (A) is not correct but (R) is correct
  3. (A) is correct but (R) is not correct
  4. Both (A) and (R) are correct but (R) is not the correct explanation of (A)
Ques. 11JEE Main 2024, 1 February (Evening Shift)

The strongest reducing agent among the following is :

  1. SbH3
  2. NH3
  3. BiH3
  4. PH3

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