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Alcohols, Phenols and Ethers

NEET 2018MCQMedium📈 Topic in 12% papers+4−1
Ques. 1NEET 2018

Identify the major products P, Q and R in the following sequence of reactions : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(4) [figure]

Solution

Friedel–Crafts alkylation: the CH3CH2 CH2 carbocation rearranges by a 1,2-hydride shift to the more stable (CH3)2 CH carbocation.

⇒ P = cumene (isopropylbenzene), not n-propylbenzene.

As per NCERT (preparation of phenol from cumene), cumene is oxidised by air to cumene hydroperoxide, which on treatment with dilute acid gives phenol and acetone.

[figure]

P = cumene, Q = phenol, R = acetone (CH3-CO-CH3).

Answer: (4)

Keep practising — Alcohols, Phenols and Ethers

Ques. 2NEET 2017

The heating of phenyl methyl ether with HI produces

  1. iodobenzene
  2. phenol
  3. benzene
  4. ethyl chloride.
Ques. 3NEET 2017

Which one is the most acidic compound?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4NEET 2016 (Phase 1)

The reaction [figure] can be classified as

  1. dehydration reaction
  2. Williamson alcohol synthesis reaction
  3. Williamson ether synthesis reaction
  4. alcohol formation reaction.
Ques. 5AIPMT 2015

Which of the following is not the product of dehydration of [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6AIPMT 2015

Reaction of phenol with chloroform in presence of dilute sodium hydroxide finally introduces which one of the following functional group?

  1. -COOH
  2. -CHCl2
  3. -CHO
  4. -CH2Cl
Ques. 7AIPMT 2015 (Cancelled)

The reaction, [figure] is called

  1. Etard reaction
  2. Gattermann-Koch reaction
  3. Williamson synthesis
  4. Williamson continuous etherification process
Ques. 8AIPMT 2014

Identify Z in the sequence of reactions: CH3CH2CH=CH2 HBr/H2O2 Y C2H5ONa Z

  1. CH3-(CH2)3-O-CH2CH3
  2. (CH3)2CH-O-CH2CH3
  3. CH3(CH2)4-O-CH3
  4. CH3CH2-CH(CH3)-O-CH2CH3
Ques. 9AIPMT 2014

Among the following sets of reactants which one produces anisole?

  1. CH3CHO ; RMgX
  2. C6H5OH ; NaOH ; CH3I
  3. C6H5OH ; neutral FeCl3
  4. C6H5CH3 ; CH3COCl ; AlCl3
Ques. 10AIPMT 2014

Which of the following will not be soluble in sodium hydrogen carbonate?

  1. 2,4,6-Trinitrophenol
  2. Benzoic acid
  3. o-Nitrophenol
  4. Benzenesulphonic acid
Ques. 11NEET 2013

Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated HI?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

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