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Aldehydes, Ketones and Carboxylic Acids

AIPMT 2002MCQEasy📈 Topic in 50% papers+4−1
Ques. 1AIPMT 2002

In the following reaction product P is R- O \|C-Cl [Pd-BaSO4]H2 P

  1. RCH2OH
  2. RCOOH
  3. RCHO
  4. RCH3

Answer

(3) RCHO

Solution

This is the Rosenmund reduction.

As per NCERT, acyl chlorides are hydrogenated over palladium on barium sulphate to give aldehydes; BaSO4 poisons the catalyst so the aldehyde is not reduced further.

RCOCl + H2 Pd-BaSO4 RCHO + HCl

Answer: (3)

Keep practising — Aldehydes, Ketones and Carboxylic Acids

Ques. 2AIPMT 2002

[figure] Product 'P' in the above reaction is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 3AIPMT 2000

First product of the reaction between RCHO and NH2NH2 is

  1. RCH=NNH2
  2. RCH=NH
  3. RCH2NH2
  4. RCON3
Ques. 4AIPMT 2000

Benzoic acid may be converted into ethyl benzoate by reaction with :

  1. ethyl alcohol
  2. ethyl alcohol and dry HCl
  3. ethyl chloride
  4. sodium ethoxide.
Ques. 5AIPMT 2000

Reduction by LiAlH4 of hydrolysed product of an ester gives

  1. two alcohols
  2. two aldehydes
  3. one acid and one alcohol
  4. two acids.

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