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d- and f-Block Elements

AIPMT 2005MCQEasy📈 Topic in 50% papers+4−1
Ques. 1AIPMT 2005

The aqueous solution containing which one of the following ions will be colourless? (Atomic number : Sc = 21, Fe = 26, Ti = 22, Mn = 25)

  1. Sc3+
  2. Fe2+
  3. Ti3+
  4. Mn2+

Answer

(1) Sc3+

Solution

Colour of transition metal ions arises from d–d transitions, which need partly filled d orbitals.

Sc3+: 3d0, Fe2+: 3d6, Ti3+: 3d1, Mn2+: 3d5

Sc3+ has no d electron, no d–d transition is possible

As per NCERT, Sc3+ (aq) is colourless.

Answer: (1)

Keep practising — d- and f-Block Elements

Ques. 2AIPMT 2004

Among K, Ca, Fe and Zn, the element which can form more than one binary compound with chlorine is

  1. Fe
  2. Zn
  3. K
  4. Ca
Ques. 3AIPMT 2004

Among the following series of transition metal ions, the one where all metal ions have 3d2 electronic configuration is [At. Nos. Ti = 22, V = 23, Cr = 24, Mn = 25]

  1. Ti3+, V2+, Cr3+, Mn4+
  2. Ti+, V4+, Cr6+, Mn7+
  3. Ti4+, V3+, Cr2+, Mn3+
  4. Ti2+, V3+, Cr4+, Mn5+
Ques. 4AIPMT 2004

Lanthanoids are

  1. 14 elements in the sixth period (atomic no. 90 to 103) that are filling 4f sublevel
  2. 14 elements in the seventh period (atomic number = 90 to 103) that are filling 5f sublevel
  3. 14 elements in the sixth period (atomic number = 58 to 71) that are filling the 4f sublevel
  4. 14 elements in the seventh period (atomic number = 50 to 71) that are filling 4f sublevel.
Ques. 5AIPMT 2003

Which one of the following characteristics of the transition metals is associated with their catalytic activity?

  1. High enthalpy of atomization
  2. Paramagnetic behaviour
  3. Colour of hydrated ions
  4. Variable oxidation states
Ques. 6AIPMT 2003

The basic character of the transition metal monoxides follows the order (Atomic nos. Ti = 22, V = 23, Cr = 24, Fe = 26)

  1. VO > CrO > TiO > FeO
  2. CrO > VO > FeO > TiO
  3. TiO > FeO > VO > CrO
  4. TiO > VO > CrO > FeO
Ques. 7AIPMT 2003

The correct order of ionic radii of Y3+, La3+, Eu3+ and Lu3+ is (Atomic nos. Y = 39, La = 57, Eu = 63, Lu = 71)

  1. Y3+ < La3+ < Eu3+ < Lu3+
  2. Y3+ < Lu3+ < Eu3+ < La3+
  3. Lu3+ < Eu3+ < La3+ < Y3+
  4. La3+ < Eu3+ < Lu3+ < Y3+
Ques. 8AIPMT 2002

General electronic configuration of lanthanides is

  1. (n-2)f1-14 (n-1)s2p6d0-1 ns2
  2. (n-2)f0-14 (n-1)d0-1 ns2
  3. (n-2)f0-14 (n-1)d10 ns2
  4. (n-2)d0-1 (n-1)f1-14 ns2
Ques. 9AIPMT 2002

Which of the following shows maximum number of oxidation states?

  1. Cr
  2. Fe
  3. Mn
  4. V
Ques. 10AIPMT 2001

Which of the following statements is not correct?

  1. La(OH)3 is less basic than Lu(OH)3.
  2. In lanthanide series ionic radius of Ln3+ ion decreases.
  3. La is actually an element of transition series rather than lanthanides.
  4. Atomic radii of Zr and Hf are nearly the same because of lanthanide contraction.
Ques. 11AIPMT 2000

Which of the following shows maximum number of oxidation states?

  1. Cr
  2. Fe
  3. Mn
  4. V

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