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d- and f-Block Elements

AIPMT 2004MCQEasy📈 Topic in 25% papers+4−1
Ques. 1AIPMT 2004

Lanthanoids are

  1. 14 elements in the sixth period (atomic no. 90 to 103) that are filling 4f sublevel
  2. 14 elements in the seventh period (atomic number = 90 to 103) that are filling 5f sublevel
  3. 14 elements in the sixth period (atomic number = 58 to 71) that are filling the 4f sublevel
  4. 14 elements in the seventh period (atomic number = 50 to 71) that are filling 4f sublevel.

Answer

(3) 14 elements in the sixth period (atomic number = 58 to 71) that are filling the 4f sublevel

Solution

As per NCERT, the lanthanoids are the 14 elements following lanthanum, from cerium (Z = 58) to lutetium (Z = 71).

They lie in the sixth period, and the differentiating electron enters the 4f subshell.

Elements with Z = 90 to 103 (thorium to lawrencium) are the actinoids of the seventh period, filling the 5f subshell.

Answer: (3)

Keep practising — d- and f-Block Elements

Ques. 2AIPMT 2003

Which one of the following characteristics of the transition metals is associated with their catalytic activity?

  1. High enthalpy of atomization
  2. Paramagnetic behaviour
  3. Colour of hydrated ions
  4. Variable oxidation states
Ques. 3AIPMT 2003

The basic character of the transition metal monoxides follows the order (Atomic nos. Ti = 22, V = 23, Cr = 24, Fe = 26)

  1. VO > CrO > TiO > FeO
  2. CrO > VO > FeO > TiO
  3. TiO > FeO > VO > CrO
  4. TiO > VO > CrO > FeO
Ques. 4AIPMT 2003

The correct order of ionic radii of Y3+, La3+, Eu3+ and Lu3+ is (Atomic nos. Y = 39, La = 57, Eu = 63, Lu = 71)

  1. Y3+ < La3+ < Eu3+ < Lu3+
  2. Y3+ < Lu3+ < Eu3+ < La3+
  3. Lu3+ < Eu3+ < La3+ < Y3+
  4. La3+ < Eu3+ < Lu3+ < Y3+
Ques. 5AIPMT 2002

General electronic configuration of lanthanides is

  1. (n-2)f1-14 (n-1)s2p6d0-1 ns2
  2. (n-2)f0-14 (n-1)d0-1 ns2
  3. (n-2)f0-14 (n-1)d10 ns2
  4. (n-2)d0-1 (n-1)f1-14 ns2
Ques. 6AIPMT 2002

Which of the following shows maximum number of oxidation states?

  1. Cr
  2. Fe
  3. Mn
  4. V
Ques. 7AIPMT 2001

Which of the following statements is not correct?

  1. La(OH)3 is less basic than Lu(OH)3.
  2. In lanthanide series ionic radius of Ln3+ ion decreases.
  3. La is actually an element of transition series rather than lanthanides.
  4. Atomic radii of Zr and Hf are nearly the same because of lanthanide contraction.
Ques. 8AIPMT 2000

Which of the following shows maximum number of oxidation states?

  1. Cr
  2. Fe
  3. Mn
  4. V
Ques. 9AIPMT 2000

Which ion is colourless?

  1. Cr4+
  2. Sc3+
  3. Ti3+
  4. V3+

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